[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate

The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]center dot 0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S, P donor set [S-Au-P angle = 178.01 (4)degrees]; a close intramolecular Au center dot center dot center dot O contact [ 2.964 (4) angstro...

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Main Authors:	Tadbuppa, P.P., Tiekink, E.R.T.
Format:	Article
Published:	International Union of Crystallography 2010
Subjects:	Q Science (General)
Online Access:	http://eprints.um.edu.my/13221/
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Institution:	Universiti Malaya

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spelling	my.um.eprints.132212019-01-30T09:01:31Z http://eprints.um.edu.my/13221/ [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate Tadbuppa, P.P. Tiekink, E.R.T. Q Science (General) The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]center dot 0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S, P donor set [S-Au-P angle = 178.01 (4)degrees]; a close intramolecular Au center dot center dot center dot O contact [ 2.964 (4) angstrom] also occurs. In the crystal structure, molecules are linked into supramolecular chains propagating along [010] by C-H center dot center dot center dot N, C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions. The solvent molecule is disordered about a twofold rotation axis. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (6). M687-U880. ISSN 1600-5368
institution	Universiti Malaya
building	UM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaya
content_source	UM Research Repository
url_provider	http://eprints.um.edu.my/
topic	Q Science (General)
spellingShingle	Q Science (General) Tadbuppa, P.P. Tiekink, E.R.T. [(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate
description	The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]center dot 0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S, P donor set [S-Au-P angle = 178.01 (4)degrees]; a close intramolecular Au center dot center dot center dot O contact [ 2.964 (4) angstrom] also occurs. In the crystal structure, molecules are linked into supramolecular chains propagating along [010] by C-H center dot center dot center dot N, C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions. The solvent molecule is disordered about a twofold rotation axis.
format	Article
author	Tadbuppa, P.P. Tiekink, E.R.T.
author_facet	Tadbuppa, P.P. Tiekink, E.R.T.
author_sort	Tadbuppa, P.P.
title	[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate
title_short	[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate
title_full	[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate
title_fullStr	[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate
title_full_unstemmed	[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate
title_sort	[(z)-o-ethyl n-(4-chlorophenyl)thiocarbamato-kappa s](triphenylphosphine-kappa p)gold(i) dichloromethane hemisolvate
publisher	International Union of Crystallography
publishDate	2010
url	http://eprints.um.edu.my/13221/
_version_	1643689493748776960

[(Z)-O-Ethyl N-(4-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) dichloromethane hemisolvate

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