(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide
The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 angstrom) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) angstrom]. The conformation about the C=N double bond [1.268 (3) angstrom] is E. An intramolecular N-H center dot center dot...
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International Union of Crystallography
2010
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my.um.eprints.132722019-01-31T04:09:55Z http://eprints.um.edu.my/13272/ (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. QD Chemistry The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 angstrom) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) angstrom]. The conformation about the C=N double bond [1.268 (3) angstrom] is E. An intramolecular N-H center dot center dot center dot N hydrogen bond occurs. Linear supramolecular chains along the b axis mediated by O-H center dot center dot center dot O hydrogen-bonding interactions feature in the crystal structure. These chains are also stabilized by weak C-H center dot center dot center dot N contacts. International Union of Crystallography 2010 Article PeerReviewed Garden, S.J. and Pinto, A.C. and da Cunha, F.R. and Fontes, S.P. and Lima, A.S. and Tiekink, E.R.T. (2010) (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide. Acta Crystallographica Section E: Structure Reports Online, 66 (6). O1436-U1657. ISSN 1600-5368 |
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QD Chemistry Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. (2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
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The title compound, C(9)H(8)Br(2)N(2)O(3), is planar (r.m.s. deviation = 0.030 angstrom) with the exception of the terminal methyl group which lies out of the plane [1.219 (3) angstrom]. The conformation about the C=N double bond [1.268 (3) angstrom] is E. An intramolecular N-H center dot center dot center dot N hydrogen bond occurs. Linear supramolecular chains along the b axis mediated by O-H center dot center dot center dot O hydrogen-bonding interactions feature in the crystal structure. These chains are also stabilized by weak C-H center dot center dot center dot N contacts. |
| format |
Article |
| author |
Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. |
| author_facet |
Garden, S.J. Pinto, A.C. da Cunha, F.R. Fontes, S.P. Lima, A.S. Tiekink, E.R.T. |
| author_sort |
Garden, S.J. |
| title |
(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_short |
(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_full |
(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_fullStr |
(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_full_unstemmed |
(2E)-N-(3,5-Dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| title_sort |
(2e)-n-(3,5-dibromo-4-methoxyphenyl)-2-(hydroxyimino)acetamide |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.um.edu.my/13272/ |
| _version_ |
1643689507477782528 |