4,5-Dihydro-3a, 5a-diazoniapyrene triiodidocuprate(I)
In the dianion of the title salt, (C14H12N2)[CuI3], the Cu-I atom is coordinated by three I- ions that define a nearly trigonalplanar geometry; the Cu-I atom lies 0.1407 (6) angstrom out of the plane. With the exception of the methylene C atoms, the dication is essentially planar (r.m.s deviation =...
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| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/14654/ |
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| Institution: | Universiti Malaya |
| Summary: | In the dianion of the title salt, (C14H12N2)[CuI3], the Cu-I atom is coordinated by three I- ions that define a nearly trigonalplanar geometry; the Cu-I atom lies 0.1407 (6) angstrom out of the plane. With the exception of the methylene C atoms, the dication is essentially planar (r.m.s deviation = 0.067 angstrom). The most significant interaction between the ions is a C-H center dot center dot center dot I contact. |
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