[(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I)
The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.1702...
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International Union of Crystallography
2010
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my.um.eprints.147742019-01-30T09:02:51Z http://eprints.um.edu.my/14774/ [(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I) Tadbuppa, P.P. Tiekink, E.R.T. QC Physics The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.1702 (16) angstrom]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis mediated by C-H center dot center dot center dot O interactions. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M429-U868. ISSN 1600-5368 |
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QC Physics Tadbuppa, P.P. Tiekink, E.R.T. [(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I) |
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The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.1702 (16) angstrom]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis mediated by C-H center dot center dot center dot O interactions. |
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Article |
author |
Tadbuppa, P.P. Tiekink, E.R.T. |
author_facet |
Tadbuppa, P.P. Tiekink, E.R.T. |
author_sort |
Tadbuppa, P.P. |
title |
[(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I) |
title_short |
[(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I) |
title_full |
[(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I) |
title_fullStr |
[(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I) |
title_full_unstemmed |
[(Z)-O-Isopropyl N-phenylthiocarbamato-kappa S](tricyclohexylphosphine- kappa P)gold(I) |
title_sort |
[(z)-o-isopropyl n-phenylthiocarbamato-kappa s](tricyclohexylphosphine- kappa p)gold(i) |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/14774/ |
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1643689897290104832 |