catena-Poly[trimethylphenylammonium [[bromidocadmate(II)]-mu-bromido-mu-chlorido]]

In the title salt, (C9H14N)[CdBr2Cl], the Cd-II atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd-II ato...

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Bibliographic Details
Main Authors: Lo, K.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Online Access:http://eprints.um.edu.my/15011/
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Institution: Universiti Malaya
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Summary:In the title salt, (C9H14N)[CdBr2Cl], the Cd-II atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd-II atoms, generating a linear polyanionic chain motif.