[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV)
The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot ce...
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my.um.eprints.152032019-01-29T08:57:35Z http://eprints.um.edu.my/15203/ [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) Lee, S.M. Ali, H.M. Lo, K.M. QC Physics The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. International Union of Crystallography 2010 Article PeerReviewed Lee, S.M. and Ali, H.M. and Lo, K.M. (2010) [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (2). M162-U717. ISSN 1600-5368 |
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QC Physics Lee, S.M. Ali, H.M. Lo, K.M. [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
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The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. |
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Article |
author |
Lee, S.M. Ali, H.M. Lo, K.M. |
author_facet |
Lee, S.M. Ali, H.M. Lo, K.M. |
author_sort |
Lee, S.M. |
title |
[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
title_short |
[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
title_full |
[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
title_fullStr |
[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
title_full_unstemmed |
[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dicyclohexyltin(IV) |
title_sort |
[n `-(5-bromo-2-oxidobenzylidene-kappa o)-3-hydroxy-2-naphthohydrazidato-kappa n-2 `,o]dicyclohexyltin(iv) |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/15203/ |
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1643690001050894336 |