mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}

mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}

The dinuclear title compound, [Pb-2(C6H8O4)(NO3)(2)(C19H13N5)(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb-II ion is covalently bonded to the nitrate anion and is bonded to a carboxylate group of the adipate unit by another covalent bo...

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Main Authors: Wei, L.Q., Zeng, M.H., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/15278/
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spelling my.um.eprints.152782019-01-30T08:25:42Z http://eprints.um.edu.my/15278/ mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)} Wei, L.Q. Zeng, M.H. Ng, S.W. QC Physics The dinuclear title compound, [Pb-2(C6H8O4)(NO3)(2)(C19H13N5)(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb-II ion is covalently bonded to the nitrate anion and is bonded to a carboxylate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Psi-octahedral coordination environment. When weaker Pb center dot center dot center dot O interactions are also considered, the geometry is a Psi-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent molecules are linked into a layer structure by N-H center dot center dot center dot O hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed Wei, L.Q. and Zeng, M.H. and Ng, S.W. (2010) mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}. Acta Crystallographica Section E: Structure Reports Online, 66 (1). M56-U629. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Wei, L.Q.
Zeng, M.H.
Ng, S.W.
mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}
description The dinuclear title compound, [Pb-2(C6H8O4)(NO3)(2)(C19H13N5)(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb-II ion is covalently bonded to the nitrate anion and is bonded to a carboxylate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom exists in a Psi-octahedral coordination environment. When weaker Pb center dot center dot center dot O interactions are also considered, the geometry is a Psi-tricapped trigonal prism in which the lone-pair electrons occupy one face of the trigonal prism. Adjacent molecules are linked into a layer structure by N-H center dot center dot center dot O hydrogen bonds.
format Article
author Wei, L.Q.
Zeng, M.H.
Ng, S.W.
author_facet Wei, L.Q.
Zeng, M.H.
Ng, S.W.
author_sort Wei, L.Q.
title mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}
title_short mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}
title_full mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}
title_fullStr mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}
title_full_unstemmed mu-Adipato-kappa O-2(1):O-4-bis{[2,6-bis(1H-benzimidazol-2-yl-kappa N-3)pyridine-kappa N](nitrato-kappa O)lead(II)}
title_sort mu-adipato-kappa o-2(1):o-4-bis{[2,6-bis(1h-benzimidazol-2-yl-kappa n-3)pyridine-kappa n](nitrato-kappa o)lead(ii)}
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/15278/
_version_ 1643690019280388096

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