Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate
In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P-C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supramolecular chains mediated by O-H center dot center dot center dot O hydrogen bonds, whic...
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2010
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my.um.eprints.153032019-01-31T04:43:51Z http://eprints.um.edu.my/15303/ Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate Mandal, T. Samanta, S. Broker, G.A. Zhao, C.G. Tiekink, E.R.T. QC Physics In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P-C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supramolecular chains mediated by O-H center dot center dot center dot O hydrogen bonds, which propagate in the a-axis direction. A C-H center dot center dot center dot O interaction consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components. International Union of Crystallography 2010 Article PeerReviewed Mandal, T. and Samanta, S. and Broker, G.A. and Zhao, C.G. and Tiekink, E.R.T. (2010) Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate. Acta Crystallographica Section E: Structure Reports Online, 66 (1). O99-U1897. ISSN 1600-5368 |
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QC Physics Mandal, T. Samanta, S. Broker, G.A. Zhao, C.G. Tiekink, E.R.T. Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate |
| description |
In the title compound, C(14)H(21)FNO(6)P, a staggered conformation about the central P-C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supramolecular chains mediated by O-H center dot center dot center dot O hydrogen bonds, which propagate in the a-axis direction. A C-H center dot center dot center dot O interaction consolidates the chains. Disorder was resolved for one of the isopropyl groups with a 0.60 (2):0.40 (2) occupancy ratio for the two components. |
| format |
Article |
| author |
Mandal, T. Samanta, S. Broker, G.A. Zhao, C.G. Tiekink, E.R.T. |
| author_facet |
Mandal, T. Samanta, S. Broker, G.A. Zhao, C.G. Tiekink, E.R.T. |
| author_sort |
Mandal, T. |
| title |
Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate |
| title_short |
Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate |
| title_full |
Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate |
| title_fullStr |
Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate |
| title_full_unstemmed |
Bis(propan-2-yl) [(1S)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate |
| title_sort |
bis(propan-2-yl) [(1s)-1-(4-fluorophenyl)-1-hydroxy-2-nitroethyl]phosphonate |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.um.edu.my/15303/ |
| _version_ |
1643690025050701824 |