Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines
A simple and elegant method for the synthesis of 1,5-benzothiazepines has been developed using di-cationic liquid as a solvent cum catalyst by the reaction of o-aminothiophenol with a variety of chalcones under mild reaction conditions. Furthermore the reusability of the catalyst has also been studi...
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my.um.eprints.208082019-04-05T07:46:38Z http://eprints.um.edu.my/20808/ Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines Sakirolla, Raghavendra Tadiparthi, Krishnaji Yaeghoobi, Marzieh Abd Rahman, Noorsaadah Q Science (General) QD Chemistry A simple and elegant method for the synthesis of 1,5-benzothiazepines has been developed using di-cationic liquid as a solvent cum catalyst by the reaction of o-aminothiophenol with a variety of chalcones under mild reaction conditions. Furthermore the reusability of the catalyst has also been studied for three cycles. All the reactions are proposed to proceed through a 1,4-conjugate Michael addition followed by a cyclo-condensation reaction. Chemic Publishing Company 2017 Article PeerReviewed Sakirolla, Raghavendra and Tadiparthi, Krishnaji and Yaeghoobi, Marzieh and Abd Rahman, Noorsaadah (2017) Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines. Asian Journal of Chemistry, 30 (1). pp. 107-115. ISSN 0970-7077 https://doi.org/10.14233/ajchem.2018.20920 doi:10.14233/ajchem.2018.20920 |
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Q Science (General) QD Chemistry Sakirolla, Raghavendra Tadiparthi, Krishnaji Yaeghoobi, Marzieh Abd Rahman, Noorsaadah Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines |
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A simple and elegant method for the synthesis of 1,5-benzothiazepines has been developed using di-cationic liquid as a solvent cum catalyst by the reaction of o-aminothiophenol with a variety of chalcones under mild reaction conditions. Furthermore the reusability of the catalyst has also been studied for three cycles. All the reactions are proposed to proceed through a 1,4-conjugate Michael addition followed by a cyclo-condensation reaction. |
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Article |
author |
Sakirolla, Raghavendra Tadiparthi, Krishnaji Yaeghoobi, Marzieh Abd Rahman, Noorsaadah |
author_facet |
Sakirolla, Raghavendra Tadiparthi, Krishnaji Yaeghoobi, Marzieh Abd Rahman, Noorsaadah |
author_sort |
Sakirolla, Raghavendra |
title |
Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines |
title_short |
Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines |
title_full |
Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines |
title_fullStr |
Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines |
title_full_unstemmed |
Di-cationic Ionic Liquid Catalyzed Synthesis of 1,5-Benzothiazepines |
title_sort |
di-cationic ionic liquid catalyzed synthesis of 1,5-benzothiazepines |
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Chemic Publishing Company |
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2017 |
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http://eprints.um.edu.my/20808/ https://doi.org/10.14233/ajchem.2018.20920 |
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1643691385765756928 |