Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bon...
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International Union of Crystallography
2012
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my.um.eprints.230942019-11-22T07:18:59Z http://eprints.um.edu.my/23094/ Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Q Science (General) QD Chemistry The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%]. International Union of Crystallography 2012 Article PeerReviewed Zhang, Kou-Lin and Lin, Jian-Guo and Ng, Seik Weng (2012) Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]. Acta Crystallographica Section E: Structure Reports Online, 68 (3). m241-m241. ISSN 1600-5368 https://doi.org/10.1107/S1600536812003613 doi:10.1107/S1600536812003613 |
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Q Science (General) QD Chemistry Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
description |
The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%]. |
format |
Article |
author |
Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng |
author_facet |
Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng |
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Zhang, Kou-Lin |
title |
Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
title_short |
Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
title_full |
Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
title_fullStr |
Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
title_full_unstemmed |
Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
title_sort |
poly[[diaqua(1,10-phenanthroline-κ2n,n′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4o1:o2,o2′:o4)dysprosium(iii)] dihydrate] |
publisher |
International Union of Crystallography |
publishDate |
2012 |
url |
http://eprints.um.edu.my/23094/ https://doi.org/10.1107/S1600536812003613 |
_version_ |
1651867398841565184 |