Intramolecular Dimerization Quenching of Delayed Emission in Asymmetric D–D′–A TADF Emitters

• Main Authors: Woon, Kai Lin, Yi, Chih-Lun, Pan, Kuan-Chung, Etherington, Marc K., Wu, Chung-Chih, Wong, Ken-Tsung, Monkman, Andrew P.
• Format: Article
• Published: American Chemical Society 2019
• Subjects: Q Science (General); QC Physics
• Online Access: http://eprints.um.edu.my/23147/; https://doi.org/10.1021/acs.jpcc.9b01900
• Institution: Universiti Malaya

Understanding the excited-state dynamics and conformational relaxation in thermally activated delayed fluorescence (TADF) molecules, including conformations that potentially support intramolecular through-space charge transfer, can open new avenues for TADF molecular design as well as elucidate comp...