Nitrophenylcarbenes. Part I. The catalytic and photolytic decomposition of α-diazo-3-nitrotoluene in the presence of olefins
The decomposition of α-diazo-3-nitrotoluene by zinc halides in the presence of olefins gave cyclopropane adducts in moderate yields. The addition of the carbenoid intermediate to unsymmetrically substituted olefins is syn-stereoselective. The free carbene species generated by photolysis also added r...
Saved in:
| Main Author: | |
|---|---|
| Format: | Article |
| Published: |
Royal Society of Chemistry
1971
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/24417/ https://doi.org/10.1039/J39710002275 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Universiti Malaya |