1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate

1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate

The title dimethyl sulfoxide (DMSO) solvate, C17H 18N4O3·C2H6OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol-ecule has non-crystallographic twofold mol-ecular symmetry. This conformation is stabilized by two intra-m...

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Main Authors: Zukerman-Schpector, Julio, Affan, Md. Abu, Foo, Siong Wan, Tiekink, Edward R.T.
Format: Article
Published: International Union of Crystallography 2009
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/25072/
https://doi.org/10.1107/S1600536809044985
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spelling my.um.eprints.250722020-07-13T03:36:07Z http://eprints.um.edu.my/25072/ 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate Zukerman-Schpector, Julio Affan, Md. Abu Foo, Siong Wan Tiekink, Edward R.T. Q Science (General) QD Chemistry The title dimethyl sulfoxide (DMSO) solvate, C17H 18N4O3·C2H6OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol-ecule has non-crystallographic twofold mol-ecular symmetry. This conformation is stabilized by two intra-molecular O- H⋯N hydrogen bonds. The components of the crystal are connected by N- H⋯O hydrogen bonds, whereby both amine H atoms are connected to a DMSO O atom, and C- H⋯O contacts involving the DMSO H and urea carbonyl atoms, forming a supra-molecular chain along the c axis. The chains associate via C- H⋯π inter-actions. International Union of Crystallography 2009 Article PeerReviewed Zukerman-Schpector, Julio and Affan, Md. Abu and Foo, Siong Wan and Tiekink, Edward R.T. (2009) 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate. Acta Crystallographica Section E: Structure Reports Online, 65 (11). o2951-o2951. ISSN 1600-5368 https://doi.org/10.1107/S1600536809044985 doi:10.1107/S1600536809044985
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zukerman-Schpector, Julio
Affan, Md. Abu
Foo, Siong Wan
Tiekink, Edward R.T.
1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
description The title dimethyl sulfoxide (DMSO) solvate, C17H 18N4O3·C2H6OS, shows the disubstituted urea derivative to adopt an almost planar geometry (r.m.s. deviation for non-H atoms = 0.132 Å); the mol-ecule has non-crystallographic twofold mol-ecular symmetry. This conformation is stabilized by two intra-molecular O- H⋯N hydrogen bonds. The components of the crystal are connected by N- H⋯O hydrogen bonds, whereby both amine H atoms are connected to a DMSO O atom, and C- H⋯O contacts involving the DMSO H and urea carbonyl atoms, forming a supra-molecular chain along the c axis. The chains associate via C- H⋯π inter-actions.
format Article
author Zukerman-Schpector, Julio
Affan, Md. Abu
Foo, Siong Wan
Tiekink, Edward R.T.
author_facet Zukerman-Schpector, Julio
Affan, Md. Abu
Foo, Siong Wan
Tiekink, Edward R.T.
author_sort Zukerman-Schpector, Julio
title 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
title_short 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
title_full 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
title_fullStr 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
title_full_unstemmed 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
title_sort 1,5-bis[(e)-1-(2-hydroxyphenyl)ethylidene]carbonohydrazide dimethyl sulfoxide solvate
publisher International Union of Crystallography
publishDate 2009
url http://eprints.um.edu.my/25072/
https://doi.org/10.1107/S1600536809044985
_version_ 1680856996219191296

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