One-pot synthesis of two new copper(i) coordination polymers: in situ formation of different ligands from 4-aminotriazole

• Main Authors: Zhao, Zhen-Guo, Yu, Rong-Min, Wu, Xiao-Yuan, Zhang, Qi-Sheng, Xie, Yi-Ming, Wang, Fei, Ng, Seik Weng, Lu, Can-Zhong
• Format: Article
• Published: Royal Society of Chemistry 2009
• Subjects: Q Science (General); QD Chemistry
• Online Access: http://eprints.um.edu.my/25093/; https://doi.org/10.1039/b821491c
• Institution: Universiti Malaya

Two Cu4I4 coordination polymers, [Cu 2I2(aadtz)]n (1) and [Cu2I(dtz)] n (2) [aadtz = 4-[(1-aminoethylidene)-amino]-3,5-diethyl-1,2,4- triazole, dtz = 3,5-diethyl-1,2,4-triazole], were synthesized in a one-pot reaction of CuI and 4-amino-3,5-diethyl-1,2,4-triazole under solvothermal conditions. The o...