4,4′-Bipyridinium tetrachloroaurate(III) chloride
The reaction of gold(III) chloride and 4,4′-bipyridine yields the compound (C10H8N2)[AuCl3] 2, which is converted to the ionic title compound (C 10H10N2)[AuCl4]Cl upon recrystallization from DMSO. The AuIII ion in the tetrachloroaurate anion exhibits a square-planar geometry; this anion is linked to...
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International Union of Crystallography
2006
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my.um.eprints.252912020-08-06T08:24:20Z http://eprints.um.edu.my/25291/ 4,4′-Bipyridinium tetrachloroaurate(III) chloride Zhang, Xiang-Pei Yang, Guang Ng, Seik Weng Q Science (General) QD Chemistry The reaction of gold(III) chloride and 4,4′-bipyridine yields the compound (C10H8N2)[AuCl3] 2, which is converted to the ionic title compound (C 10H10N2)[AuCl4]Cl upon recrystallization from DMSO. The AuIII ion in the tetrachloroaurate anion exhibits a square-planar geometry; this anion is linked to the bipyridinium cation by an N-H⋯Cl hydrogen bond to form chains which extend parallel to the b axis. The bipyridinium cation exhibits 2 symmetry, whereas the tetrachloroaurate anion shows 2/m symmetry, and the chloride anion is located on a position with 222 symmetry. © 2006 International Union of Crystallography. All rights reserved. International Union of Crystallography 2006 Article PeerReviewed Zhang, Xiang-Pei and Yang, Guang and Ng, Seik Weng (2006) 4,4′-Bipyridinium tetrachloroaurate(III) chloride. Acta Crystallographica Section E: Structure Reports Online, 62 (9). m2018-m2020. ISSN 1600-5368 https://doi.org/10.1107/S1600536806029199 doi:10.1107/S1600536806029199 |
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Q Science (General) QD Chemistry Zhang, Xiang-Pei Yang, Guang Ng, Seik Weng 4,4′-Bipyridinium tetrachloroaurate(III) chloride |
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The reaction of gold(III) chloride and 4,4′-bipyridine yields the compound (C10H8N2)[AuCl3] 2, which is converted to the ionic title compound (C 10H10N2)[AuCl4]Cl upon recrystallization from DMSO. The AuIII ion in the tetrachloroaurate anion exhibits a square-planar geometry; this anion is linked to the bipyridinium cation by an N-H⋯Cl hydrogen bond to form chains which extend parallel to the b axis. The bipyridinium cation exhibits 2 symmetry, whereas the tetrachloroaurate anion shows 2/m symmetry, and the chloride anion is located on a position with 222 symmetry. © 2006 International Union of Crystallography. All rights reserved. |
| format |
Article |
| author |
Zhang, Xiang-Pei Yang, Guang Ng, Seik Weng |
| author_facet |
Zhang, Xiang-Pei Yang, Guang Ng, Seik Weng |
| author_sort |
Zhang, Xiang-Pei |
| title |
4,4′-Bipyridinium tetrachloroaurate(III) chloride |
| title_short |
4,4′-Bipyridinium tetrachloroaurate(III) chloride |
| title_full |
4,4′-Bipyridinium tetrachloroaurate(III) chloride |
| title_fullStr |
4,4′-Bipyridinium tetrachloroaurate(III) chloride |
| title_full_unstemmed |
4,4′-Bipyridinium tetrachloroaurate(III) chloride |
| title_sort |
4,4′-bipyridinium tetrachloroaurate(iii) chloride |
| publisher |
International Union of Crystallography |
| publishDate |
2006 |
| url |
http://eprints.um.edu.my/25291/ https://doi.org/10.1107/S1600536806029199 |
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