2d sp(2) carbon-conjugated covalent organic framework with pyrene-tethered tempo intercalation for photocatalytic aerobic oxidation of sulfides into sulfoxides

• Main Authors: Shi, Ji-Long, Feng, Keyu, Hao, Huimin, Ku, Calvin, Sit, Patrick H-L, Teoh, Wey Yang, Lang, Xianjun
• Format: Article
• Published: Wiley-V C H Verlag GMBH 2022
• Subjects: QD Chemistry; TA Engineering (General). Civil engineering (General); TP Chemical technology
• Online Access: http://eprints.um.edu.my/33692/
• Institution: Universiti Malaya

The 2D covalent organic frameworks (COFs) offer many 2D planes which are suitable for pi-pi stacking interactions with other conjugated molecules. To improve the photocatalytic performance of COFs, the synthesis of a pyrene-tethered 2,2,6,6-tetramethylpiperidinyl-N-oxyl (TEMPO) derivative cocatalyst...