Ethylsulphate based ionic liquids for denitification of liquid fuels
Ternary liquid-liquid equilibrium (LLE) for eight systems containing 1-ethyl-3-methylimidazolium ethylsulphate {EMIM]EtSO4]}, 1-ethyl-3-methylpyridinium ethylsulphate {EMPy]EtSO4]} (1) + pyridine/pyrrole/indoline/quinoline (2) + dodecene (3) have been determined at 298.15 K. The reliability of exper...
محفوظ في:
| المؤلفون الرئيسيون: | , |
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| التنسيق: | مقال |
| منشور في: |
Taylor & Francis Inc
2022
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| الموضوعات: | |
| الوصول للمادة أونلاين: | http://eprints.um.edu.my/42403/ |
| الوسوم: |
إضافة وسم
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| المؤسسة: | Universiti Malaya |
| الملخص: | Ternary liquid-liquid equilibrium (LLE) for eight systems containing 1-ethyl-3-methylimidazolium ethylsulphate {EMIM]EtSO4]}, 1-ethyl-3-methylpyridinium ethylsulphate {EMPy]EtSO4]} (1) + pyridine/pyrrole/indoline/quinoline (2) + dodecene (3) have been determined at 298.15 K. The reliability of experimental LLE data was tested by Othmer-Tobias and Hand equations. The NRTL and UNIQUAC models were successfully used for experimental LLE data correlation and gave the RMSD less than unity, which indicated a good degree of experimental LLE data fit. Distribution coefficient and the selectivity of EMIM]EtSO4] and EMPy]EtSO4] were calculated for all the studied systems. Here, high distribution coefficient and selectivity were obtained for the removal of pyridine/pyrrole/indoline/quinoline from dodecene using EMIM]EtSO4] and EMPy]EtSO4] ionic liquids at 298.15 K. |
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