Switching thermally activated delayed fluorescence to room temperature phosphorescence for oxygen sensing: Effect of donor substituents of trifluoromethylphenyl

• Main Authors: Skhirtladze, Levani, Keruckiene, Rasa, Bezvikonnyi, Oleksandr, Mahmoudi, Malek, Volyniuk, Dmytro, Leitonas, Karolis, Ghasemi, Melika, Simokaitiene, Jurate, Nasir, Farah Hannan Abd, Ariffin, Azhar, V. Grazulevicius, Juozas
• Format: Article
• Published: PERGAMON-ELSEVIER SCIENCE LTD 2024
• Subjects: TP Chemical technology
• Online Access: http://eprints.um.edu.my/44305/; https://doi.org/10.1016/j.saa.2023.123531
• Institution: Universiti Malaya

Two compounds consisting of electron-accepting trifluoromethylphenyl moiety and electron-donating phenoxazine and phenothiazine moieties were designed and synthesized via Buchwald-Hartwig coupling reaction. Thermal, photophysical, and electrochemical properties of the compounds are discussed. Only compound with phenothiazine form molecular glass, with glass transition temperatures of 90 degrees C. The geometry and electronic characteristics of the compounds were substantiated within density functional theory (DFT). 10,10 `-(2-(Trifluoromethyl)-1,4-phenylene)bis(10H-phenoxazine) shows efficient thermally activated delayed fluorescence with high spin-orbit coupling values. 10,10 `-(2-(Trifluoromethyl)-1,4-phenylene)bis(10H-phenothiazine) as efficient room-temperature phosphor shows high oxygen sensitivity.