Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy
The realization of sodium-ion devices with high-power density and long-cycle capability is challenging due to the difficulties of carrier diffusion and electrode fragmentation in transition metal selenide anodes. Herein, a Mo/W-based metal-organic framework is constructed by a one-step method throug...
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my.um.eprints.454032024-10-21T02:57:19Z http://eprints.um.edu.my/45403/ Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy Wang, Jian Shao, Yachuan Ma, Yanqiang Zhang, Di Aziz, Shujahadeen B. Li, Zhaojin Woo, Haw Jiunn Subramaniam, Ramesh T. Wang, Bo Q Science (General) QC Physics The realization of sodium-ion devices with high-power density and long-cycle capability is challenging due to the difficulties of carrier diffusion and electrode fragmentation in transition metal selenide anodes. Herein, a Mo/W-based metal-organic framework is constructed by a one-step method through rational selection, after which MoWSe/C heterostructures with large angles are synthesized by a facile selenization/carbonization strategy. Through physical characterization and theoretical calculations, the synthesized MoWSe/C electrode delivers obvious structural advantages and excellent electrochemical performance in an ethylene glycol dimethyl ether electrolyte. Furthermore, the electrochemical vehicle mechanism of ions in the electrolyte is systematically revealed through comparative analyses. Resultantly, ether-based electrolytes advantageously construct stable solid electrolyte interfaces and avoid electrolyte decomposition. Based on the above benefits, the Na half-cell assembled with MoWSe/C electrodes demonstrated excellent rate capability and a high specific capacity of 347.3 mA h g(-1) even after cycling 2000 cycles at 10 A g(-1). Meanwhile, the constructed sodium-ion capacitor maintains similar to 80% capacity retention after 11,000 ultralong cycles at a high-power density of 3800 W kg(-1). The findings can broaden the mechanistic understanding of conversion anodes in different electrolytes and provide a reference for the structural design of anodes with high capacity, fast kinetics, and long-cycle stability. American Chemical Society 2024-03 Article PeerReviewed Wang, Jian and Shao, Yachuan and Ma, Yanqiang and Zhang, Di and Aziz, Shujahadeen B. and Li, Zhaojin and Woo, Haw Jiunn and Subramaniam, Ramesh T. and Wang, Bo (2024) Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy. ACS Nano, 18 (14). pp. 10230-10242. ISSN 1936-0851, DOI https://doi.org/10.1021/acsnano.4c00599 <https://doi.org/10.1021/acsnano.4c00599>. https://doi.org/10.1021/acsnano.4c00599 10.1021/acsnano.4c00599 |
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Q Science (General) QC Physics Wang, Jian Shao, Yachuan Ma, Yanqiang Zhang, Di Aziz, Shujahadeen B. Li, Zhaojin Woo, Haw Jiunn Subramaniam, Ramesh T. Wang, Bo Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy |
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The realization of sodium-ion devices with high-power density and long-cycle capability is challenging due to the difficulties of carrier diffusion and electrode fragmentation in transition metal selenide anodes. Herein, a Mo/W-based metal-organic framework is constructed by a one-step method through rational selection, after which MoWSe/C heterostructures with large angles are synthesized by a facile selenization/carbonization strategy. Through physical characterization and theoretical calculations, the synthesized MoWSe/C electrode delivers obvious structural advantages and excellent electrochemical performance in an ethylene glycol dimethyl ether electrolyte. Furthermore, the electrochemical vehicle mechanism of ions in the electrolyte is systematically revealed through comparative analyses. Resultantly, ether-based electrolytes advantageously construct stable solid electrolyte interfaces and avoid electrolyte decomposition. Based on the above benefits, the Na half-cell assembled with MoWSe/C electrodes demonstrated excellent rate capability and a high specific capacity of 347.3 mA h g(-1) even after cycling 2000 cycles at 10 A g(-1). Meanwhile, the constructed sodium-ion capacitor maintains similar to 80% capacity retention after 11,000 ultralong cycles at a high-power density of 3800 W kg(-1). The findings can broaden the mechanistic understanding of conversion anodes in different electrolytes and provide a reference for the structural design of anodes with high capacity, fast kinetics, and long-cycle stability. |
format |
Article |
author |
Wang, Jian Shao, Yachuan Ma, Yanqiang Zhang, Di Aziz, Shujahadeen B. Li, Zhaojin Woo, Haw Jiunn Subramaniam, Ramesh T. Wang, Bo |
author_facet |
Wang, Jian Shao, Yachuan Ma, Yanqiang Zhang, Di Aziz, Shujahadeen B. Li, Zhaojin Woo, Haw Jiunn Subramaniam, Ramesh T. Wang, Bo |
author_sort |
Wang, Jian |
title |
Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy |
title_short |
Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy |
title_full |
Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy |
title_fullStr |
Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy |
title_full_unstemmed |
Facilitating Rapid Na+ Storage through MoWSe/C Heterostructure Construction and Synergistic Electrolyte Matching Strategy |
title_sort |
facilitating rapid na+ storage through mowse/c heterostructure construction and synergistic electrolyte matching strategy |
publisher |
American Chemical Society |
publishDate |
2024 |
url |
http://eprints.um.edu.my/45403/ https://doi.org/10.1021/acsnano.4c00599 |
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1814047554073001984 |