Synthesis, fabrication and characterization of CaMgFexTiyO12-based electro-ceramics sensor

The present study aims to fabricate a novel multiphase ceramic-nanocomposite having giant dielectric constant and minimum dielectric loss. Under a high palletization pressure along with novel step-sintering has played a vital role to improve the porosity, reduce the density and grain-boundary resist...

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Bibliographic Details
Main Authors: Tripathy, Ashis, Sharma, Priyaranjan, Abu Osman, Noor Azuan
Format: Article
Published: Springer 2024
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Online Access:http://eprints.um.edu.my/45532/
https://doi.org/10.1007/s10854-024-12100-x
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Institution: Universiti Malaya
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Summary:The present study aims to fabricate a novel multiphase ceramic-nanocomposite having giant dielectric constant and minimum dielectric loss. Under a high palletization pressure along with novel step-sintering has played a vital role to improve the porosity, reduce the density and grain-boundary resistance leading to enhanced dielectric characteristics. The formation of different phases in developed nanocomposite is evaluated by XRD analysis. Frequency-dependent impedance spectroscopy of developed electro-ceramic reveals the better impedance, electrical modulus, dielectric permittivity (epsilon'), loss-tangent (tan delta), and water physisorption capacity compared to unsintered compound and other existing ceramic compounds. The developed sensor exhibits high sensitivity up to 0.27 M Omega/Delta% RH, fast response (19.37 s) and recovery time (39.17 s) as well as low hysteresis of similar to 3.31% (for the impedance) and similar to 3.29% (for capacitive) at 100 Hz. Therefore, the developed nano-electronic ceramic seems to be a very promising material for manufacturing high-efficiency humidity sensors.