Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc

In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination en...

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Bibliographic Details
Main Authors: Hisham, N.A.I., Ali, Hapipah Mohd, Khaledi, H.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
Online Access:http://eprints.um.edu.my/5232/1/Hisham-2011-Dichlorido%282-%7B_3-%28mo.pdf
http://eprints.um.edu.my/5232/
http://scripts.iucr.org/cgi-bin/paper?S1600536811022021
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Institution: Universiti Malaya
Language: English
Description
Summary:In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N-H center dot center dot center dot O hydrogen bonds connect the molecules into a centrosymmetric dimer. C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also observed.