Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)

The asymmetric unit of the title compound, [MnCl2(C11H17N3)], contains two crystallographically independent molecules with slightly different geometries. In each molecule, the Mn-II ion is five coordinated by the N,N',N ''-tridentate Schiff base and two Cl atoms in a distorted square-...

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Main Authors: Hisham, N.A.I., Ali, Hapipah Mohd, Khaledi, H., Gwaram, N.S.
Format: Article
Language:English
Published: International Union of Crystallography 2011
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Online Access:http://eprints.um.edu.my/5237/1/Hisham-2011-Dichlorido%7BN%2CN-dimet.pdf
http://eprints.um.edu.my/5237/
http://journals.iucr.org/e/issues/2011/02/00/is2666/is2666.pdf
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spelling my.um.eprints.52372019-01-30T00:58:20Z http://eprints.um.edu.my/5237/ Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II) Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Gwaram, N.S. QD Chemistry The asymmetric unit of the title compound, [MnCl2(C11H17N3)], contains two crystallographically independent molecules with slightly different geometries. In each molecule, the Mn-II ion is five coordinated by the N,N',N ''-tridentate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. In the crystal, C-H center dot center dot center dot Cl hydrogen bonds link adjacent molecules into a three-dimensional network. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5237/1/Hisham-2011-Dichlorido%7BN%2CN-dimet.pdf Hisham, N.A.I. and Ali, Hapipah Mohd and Khaledi, H. and Gwaram, N.S. (2011) Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II). Acta Crystallographica Section E: Structure Reports Online, 67. M229-U1113. ISSN 1600-5368 http://journals.iucr.org/e/issues/2011/02/00/is2666/is2666.pdf 10.1107/s1600536811002030
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Hisham, N.A.I.
Ali, Hapipah Mohd
Khaledi, H.
Gwaram, N.S.
Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)
description The asymmetric unit of the title compound, [MnCl2(C11H17N3)], contains two crystallographically independent molecules with slightly different geometries. In each molecule, the Mn-II ion is five coordinated by the N,N',N ''-tridentate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. In the crystal, C-H center dot center dot center dot Cl hydrogen bonds link adjacent molecules into a three-dimensional network.
format Article
author Hisham, N.A.I.
Ali, Hapipah Mohd
Khaledi, H.
Gwaram, N.S.
author_facet Hisham, N.A.I.
Ali, Hapipah Mohd
Khaledi, H.
Gwaram, N.S.
author_sort Hisham, N.A.I.
title Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)
title_short Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)
title_full Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)
title_fullStr Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)
title_full_unstemmed Dichlorido{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''} manganese(II)
title_sort dichlorido{n,n-dimethyl-n '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa n-3,n ',n ''} manganese(ii)
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/5237/1/Hisham-2011-Dichlorido%7BN%2CN-dimet.pdf
http://eprints.um.edu.my/5237/
http://journals.iucr.org/e/issues/2011/02/00/is2666/is2666.pdf
_version_ 1643687522214084608