Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II)
In the title compound, [Ni(NCS)(2)(C11H17N3)(H2O)], the NiII ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O-H...S hydrogen bonds link adjacent molecules into infinite layers pa...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5240/1/Gwaram-2011-Aqua%7BN%2CN-dimethyl-N.pdf http://eprints.um.edu.my/5240/ http://scripts.iucr.org/cgi-bin/paper?S1600536811011512 |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | In the title compound, [Ni(NCS)(2)(C11H17N3)(H2O)], the NiII ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O-H...S hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H...pi interactions. The -CH2-N(CH3)(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio. |
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