Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)nickel(II)

Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)nickel(II)

In the title compound, [Ni(NCS)(2)(C13H19N3O)(H2O)], the Ni-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water O atom in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H...

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Bibliographic Details
Main Authors: Gwaram, N.S., Ali, Hapipah Mohd, Khaledi, H., Hisham, N.A.I.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5255/1/Gwaram-2011-Aqua%7B2-morpholino-N-.pdf
http://eprints.um.edu.my/5255/
http://scripts.iucr.org/cgi-bin/paper?S1600536810052578
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Institution: Universiti Malaya
Language: English
Description
Summary:In the title compound, [Ni(NCS)(2)(C13H19N3O)(H2O)], the Ni-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water O atom in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds occur. In the crystal, O-H center dot center dot center dot S, O-H center dot center dot center dot O and C-H center dot center dot center dot S hydrogen bonds link adjacent molecules into layers parallel to the ac plane.

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