N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)

The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond between the amido N atom...

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Main Authors:	Lee, S.M., Lo, K.M., Ali, Hapipah Mohd
Format:	Article
Language:	English
Published:	International Union of Crystallography 2010
Subjects:	QD Chemistry
Online Access:	http://eprints.um.edu.my/5281/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf http://eprints.um.edu.my/5281/ http://scripts.iucr.org/cgi-bin/paper?S1600536810001133
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Institution:	Universiti Malaya
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id	my.um.eprints.5281
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spelling	my.um.eprints.52812019-01-29T08:57:06Z http://eprints.um.edu.my/5281/ N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV) Lee, S.M. Lo, K.M. Ali, Hapipah Mohd QD Chemistry The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond between the amido N atom and hydroxy H atom in the Schiff base ligand helps to stabilize the overall molecular structure. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5281/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf Lee, S.M. and Lo, K.M. and Ali, Hapipah Mohd (2010) N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M161-U706. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536810001133 10.1107/s1600536810001133
institution	Universiti Malaya
building	UM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaya
content_source	UM Research Repository
url_provider	http://eprints.um.edu.my/
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Lee, S.M. Lo, K.M. Ali, Hapipah Mohd N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)
description	The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond between the amido N atom and hydroxy H atom in the Schiff base ligand helps to stabilize the overall molecular structure.
format	Article
author	Lee, S.M. Lo, K.M. Ali, Hapipah Mohd
author_facet	Lee, S.M. Lo, K.M. Ali, Hapipah Mohd
author_sort	Lee, S.M.
title	N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)
title_short	N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)
title_full	N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)
title_fullStr	N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)
title_full_unstemmed	N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)
title_sort	n '-(5-bromo-2-oxidobenzylidene-kappa o)-3-hydroxy-2-naphthohydrazidato-kappa n-2 ',o dimethyltin(iv)
publisher	International Union of Crystallography
publishDate	2010
url	http://eprints.um.edu.my/5281/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf http://eprints.um.edu.my/5281/ http://scripts.iucr.org/cgi-bin/paper?S1600536810001133
_version_	1643687533584842752

N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dimethyltin(IV)

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