Bis{μ-2-(1H-indol-3-yl)-N'-[1-(5-methyl-2-oxidophen-yl)ethyl-idene]-aceto-hydraz-idato}bis-[aqua-zinc(II)] dimethyl sulfoxide tetra-solvate
The dinuclear title compound, [Zn(2)(C(19)H(17)N(3)O(2))(2)(H(2)O)(2)]·4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydr-oxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square aroun...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5463/1/Zuraini-2008-Bis%7B%CE%BC-2-%281H-indol-3-.pdf http://eprints.um.edu.my/5463/ https://doi.org/10.1107/S1600536808022034 |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | The dinuclear title compound, [Zn(2)(C(19)H(17)N(3)O(2))(2)(H(2)O)(2)]·4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydr-oxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal. The coordination geometry is square-pyramidal, with the apical site occupied by a water mol-ecule. Hydrogen bonds, with the water mol-ecule serving as donor atom, lead to the formation of a linear chain motif. There is an N-H⋯O hydrogen bond between the complex molecule and solvent O atom. |
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