1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)

1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)

The Zn-II atom in the title compound, [Zn(C14H11N3O2S)-(C12H8N2)]center dot 0.5C(10)H(8)N(2), is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4 '-b...

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Main Authors: Tan, Kong Wai, Ng, S.W., Maah, Mohd Jamil, Ng, C.H.
Format: Article
Language:English
Published: International Union of Crystallography 2009
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/6958/1/Tan-2009-1-%284-Hydroxy-2-oxido.pdf
http://eprints.um.edu.my/6958/
http://journals.iucr.org/e/issues/2009/08/00/tk2484/tk2484.pdf
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spelling my.um.eprints.69582019-01-30T09:06:15Z http://eprints.um.edu.my/6958/ 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1) Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. QD Chemistry The Zn-II atom in the title compound, [Zn(C14H11N3O2S)-(C12H8N2)]center dot 0.5C(10)H(8)N(2), is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4 '-bipyridine, which is located about a center of inversion, resulting in the formation of a supramolecular trimeric unit. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6958/1/Tan-2009-1-%284-Hydroxy-2-oxido.pdf Tan, Kong Wai and Ng, S.W. and Maah, Mohd Jamil and Ng, C.H. (2009) 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1). Acta Crystallographica Section E: Structure Reports Online, 65. M920-U922. ISSN 1600-5368 http://journals.iucr.org/e/issues/2009/08/00/tk2484/tk2484.pdf 10.1107/s1600536809026245
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Tan, Kong Wai
Ng, S.W.
Maah, Mohd Jamil
Ng, C.H.
1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)
description The Zn-II atom in the title compound, [Zn(C14H11N3O2S)-(C12H8N2)]center dot 0.5C(10)H(8)N(2), is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4 '-bipyridine, which is located about a center of inversion, resulting in the formation of a supramolecular trimeric unit.
format Article
author Tan, Kong Wai
Ng, S.W.
Maah, Mohd Jamil
Ng, C.H.
author_facet Tan, Kong Wai
Ng, S.W.
Maah, Mohd Jamil
Ng, C.H.
author_sort Tan, Kong Wai
title 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)
title_short 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)
title_full 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)
title_fullStr 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)
title_full_unstemmed 1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa N-3,O,S (1,10-phenanthroline-kappa N-2,N ')zinc(II)-4,4 '-bipyridine (2/1)
title_sort 1-(4-hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-kappa n-3,o,s (1,10-phenanthroline-kappa n-2,n ')zinc(ii)-4,4 '-bipyridine (2/1)
publisher International Union of Crystallography
publishDate 2009
url http://eprints.um.edu.my/6958/1/Tan-2009-1-%284-Hydroxy-2-oxido.pdf
http://eprints.um.edu.my/6958/
http://journals.iucr.org/e/issues/2009/08/00/tk2484/tk2484.pdf
_version_ 1643687926978052096

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