Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine
The equilibrium constant for the formation of diethanolamine carbamate was determined experimentally at (303, 313, 323, and 331) K for ionic strengths up to 1.8 mol dm-3, the inert electrolyte being NaClO4. A linear relationship was found to hold between log K and I0.5. The thermodynamical constant...
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American Chemical Society
1997
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my.um.eprints.75112019-05-31T04:16:35Z http://eprints.um.edu.my/7511/ Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine Aroua, Mohamed Kheireddine Amor, A.B. Haji-Sulaiman, M.Z. TA Engineering (General). Civil engineering (General) TP Chemical technology The equilibrium constant for the formation of diethanolamine carbamate was determined experimentally at (303, 313, 323, and 331) K for ionic strengths up to 1.8 mol dm-3, the inert electrolyte being NaClO4. A linear relationship was found to hold between log K and I0.5. The thermodynamical constant has been determined and expressed by the equation log K1 = -5.12 + 1.781 × 103 K/T. American Chemical Society 1997 Article PeerReviewed Aroua, Mohamed Kheireddine and Amor, A.B. and Haji-Sulaiman, M.Z. (1997) Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine. Journal of Chemical and Engineering Data, 42 (4). pp. 692-696. ISSN 0021-9568 http://pubs.acs.org/doi/abs/10.1021/je970004s Doi 10.1021/Je970004s |
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TA Engineering (General). Civil engineering (General) TP Chemical technology |
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TA Engineering (General). Civil engineering (General) TP Chemical technology Aroua, Mohamed Kheireddine Amor, A.B. Haji-Sulaiman, M.Z. Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine |
| description |
The equilibrium constant for the formation of diethanolamine carbamate was determined experimentally at (303, 313, 323, and 331) K for ionic strengths up to 1.8 mol dm-3, the inert electrolyte being NaClO4. A linear relationship was found to hold between log K and I0.5. The thermodynamical constant has been determined and expressed by the equation log K1 = -5.12 + 1.781 × 103 K/T. |
| format |
Article |
| author |
Aroua, Mohamed Kheireddine Amor, A.B. Haji-Sulaiman, M.Z. |
| author_facet |
Aroua, Mohamed Kheireddine Amor, A.B. Haji-Sulaiman, M.Z. |
| author_sort |
Aroua, Mohamed Kheireddine |
| title |
Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine |
| title_short |
Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine |
| title_full |
Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine |
| title_fullStr |
Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine |
| title_full_unstemmed |
Temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine |
| title_sort |
temperature dependency of the equilibrium constant for the formation of carbamate from diethanolamine |
| publisher |
American Chemical Society |
| publishDate |
1997 |
| url |
http://eprints.um.edu.my/7511/ http://pubs.acs.org/doi/abs/10.1021/je970004s |
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