4-[(9-Ethyl-9H-carbazol-3-yl)methylideneamino]-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one

The imino-carbon double bond in the title Schiff base, C(26)H(24)N(4)O, has an E configuration. The 13-membered carbazolyl fused-ring (r.m.s. deviation = 0.056 angstrom) is nearly coplanar with five-membered pyrazole ring (r.m.s. deviation = 0.036 angstrom) [dihedral angle between the two systems =...

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Bibliographic Details
Main Authors: Tan, Kong Wai, Ng, S.W., Asiri, A.M., Khan, S.A.
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
Online Access:http://eprints.um.edu.my/8020/1/Asiri-2010-4-_%289-Ethyl-9H-carba.pdf
http://eprints.um.edu.my/8020/
http://journals.iucr.org/e/issues/2010/07/00/jh2169/jh2169.pdf
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Institution: Universiti Malaya
Language: English
Description
Summary:The imino-carbon double bond in the title Schiff base, C(26)H(24)N(4)O, has an E configuration. The 13-membered carbazolyl fused-ring (r.m.s. deviation = 0.056 angstrom) is nearly coplanar with five-membered pyrazole ring (r.m.s. deviation = 0.036 angstrom) [dihedral angle between the two systems = 10.4 (1)degrees]; the phenyl substituent is twisted by 51.1 (1)degrees with respect to the five-membered ring.