A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol
In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 angstrom) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 angstrom), the two rings being slightly bent at 2.6 (1)degrees. The hydroxy H ato...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/8021/1/Asiri-2010-A_monoclinic_modific.pdf http://eprints.um.edu.my/8021/ http://journals.iucr.org/e/issues/2010/07/00/nk2043/nk2043.pdf |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 angstrom) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 angstrom), the two rings being slightly bent at 2.6 (1)degrees. The hydroxy H atom forms an intramolecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the orthorhombic modification [Liu et al. (2009). Acta Cryst. E65, o738]. |
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