Fast Photoswitching Azo Dyes

Fast photoswitching azobenzene molecules were incorporated into isoflavone moieties. These molecules exhibit a liquid crystalline nematic state at certain temperature intervals. UV/Vis spectrophotometry investigations on solutions reveal that E/Z conversion takes place around 1 s, whereas thermal ba...

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Bibliographic Details
Main Authors: Hegde, Gurumurthy, Yuvaraj, A. R., Wan, Sinn Yam, M. M., Yusoff
Format: Article
Published: John Wiley & Sons 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/10125/
http://dx.doi.org/10.1002/masy.201550333
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Institution: Universiti Malaysia Pahang
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Summary:Fast photoswitching azobenzene molecules were incorporated into isoflavone moieties. These molecules exhibit a liquid crystalline nematic state at certain temperature intervals. UV/Vis spectrophotometry investigations on solutions reveal that E/Z conversion takes place around 1 s, whereas thermal back relaxation, namely Z/E, takes around 6 min. This is the first example of fast photoswitching isoflavones in solution. This study has potential to create optical data storage devices when transferred to solid surfaces.