Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate
Glycerol carbonate can be readily synthesized from glycerol and urea catalyzed by PdZnO, PdSnO2, SnO2, and ZnO. The superior catalytic activity of ZnO over SnO2 is mainly due to basicity property. The incorporation of low metal loading of Pd on both SnO2 and ZnO produced higher yield of glycerol car...
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Asian Online Journals
2016
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Online Access: | http://umpir.ump.edu.my/id/eprint/13486/1/Low%20Metal%20Loading%20Palladium%20Mixed-Oxides%20Catalyst%20for%20the%20Synthesis%20of%20Glycerol%20Carbonate.pdf http://umpir.ump.edu.my/id/eprint/13486/ http://www.ajouronline.com/index.php?journal=AJAS&page=article&op=view&path%5B%5D=3107 |
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my.ump.umpir.134862020-02-28T03:45:15Z http://umpir.ump.edu.my/id/eprint/13486/ Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate Anisah Sajidah, Haji Saud Indran, Vidhyaa Paroo Nazira, Mahmud Mohd Hasbi, Ab. Rahim QD Chemistry Glycerol carbonate can be readily synthesized from glycerol and urea catalyzed by PdZnO, PdSnO2, SnO2, and ZnO. The superior catalytic activity of ZnO over SnO2 is mainly due to basicity property. The incorporation of low metal loading of Pd on both SnO2 and ZnO produced higher yield of glycerol carbonate to bulk material counterpart. In addition, the sol-gel technique was shown to have higher turn-over frequency (TOF) due to highly disperse Pd with small crystallite size. Asian Online Journals 2016-02 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/13486/1/Low%20Metal%20Loading%20Palladium%20Mixed-Oxides%20Catalyst%20for%20the%20Synthesis%20of%20Glycerol%20Carbonate.pdf Anisah Sajidah, Haji Saud and Indran, Vidhyaa Paroo and Nazira, Mahmud and Mohd Hasbi, Ab. Rahim (2016) Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate. Asian Journal of Applied Sciences, 4 (1). pp. 181-189. ISSN 2321–0893. (Published) http://www.ajouronline.com/index.php?journal=AJAS&page=article&op=view&path%5B%5D=3107 |
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QD Chemistry Anisah Sajidah, Haji Saud Indran, Vidhyaa Paroo Nazira, Mahmud Mohd Hasbi, Ab. Rahim Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate |
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Glycerol carbonate can be readily synthesized from glycerol and urea catalyzed by PdZnO, PdSnO2, SnO2, and ZnO. The superior catalytic activity of ZnO over SnO2 is mainly due to basicity property. The incorporation of low metal loading of Pd on both SnO2 and ZnO produced higher yield of glycerol carbonate to bulk material counterpart. In addition, the sol-gel technique was shown to have higher turn-over frequency (TOF) due to highly disperse Pd with small crystallite size. |
format |
Article |
author |
Anisah Sajidah, Haji Saud Indran, Vidhyaa Paroo Nazira, Mahmud Mohd Hasbi, Ab. Rahim |
author_facet |
Anisah Sajidah, Haji Saud Indran, Vidhyaa Paroo Nazira, Mahmud Mohd Hasbi, Ab. Rahim |
author_sort |
Anisah Sajidah, Haji Saud |
title |
Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate |
title_short |
Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate |
title_full |
Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate |
title_fullStr |
Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate |
title_full_unstemmed |
Low Metal Loading Palladium Mixed-Oxides Catalyst for the Synthesis of Glycerol Carbonate |
title_sort |
low metal loading palladium mixed-oxides catalyst for the synthesis of glycerol carbonate |
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Asian Online Journals |
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2016 |
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http://umpir.ump.edu.my/id/eprint/13486/1/Low%20Metal%20Loading%20Palladium%20Mixed-Oxides%20Catalyst%20for%20the%20Synthesis%20of%20Glycerol%20Carbonate.pdf http://umpir.ump.edu.my/id/eprint/13486/ http://www.ajouronline.com/index.php?journal=AJAS&page=article&op=view&path%5B%5D=3107 |
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