Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts

Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as...

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Main Authors: Nur Nabillah, Mohd Arif, Vo, Dai-Viet N., Mohammad Tazli, Azizan, Sumaiya, Zainal Abidin
Format: Article
Language:English
Published: Department of Chemical Engineering, Diponegoro University 2016
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Online Access:http://umpir.ump.edu.my/id/eprint/17403/1/fkksa-2016-sumaiya-Carbon%20Dioxide%20Dry%20Reforming%20of%20Glycerol%20for%20Hydrogen.pdf
http://umpir.ump.edu.my/id/eprint/17403/
http://dx.doi.org/10.9767/bcrec.11.2.551.200-209
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Institution: Universiti Malaysia Pahang Al-Sultan Abdullah
Language: English
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spelling my.ump.umpir.174032019-10-30T03:29:28Z http://umpir.ump.edu.my/id/eprint/17403/ Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts Nur Nabillah, Mohd Arif Vo, Dai-Viet N. Mohammad Tazli, Azizan Sumaiya, Zainal Abidin TP Chemical technology Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out us-ing Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gra-vimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallin-ity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET. Department of Chemical Engineering, Diponegoro University 2016 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/17403/1/fkksa-2016-sumaiya-Carbon%20Dioxide%20Dry%20Reforming%20of%20Glycerol%20for%20Hydrogen.pdf Nur Nabillah, Mohd Arif and Vo, Dai-Viet N. and Mohammad Tazli, Azizan and Sumaiya, Zainal Abidin (2016) Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2). pp. 200-209. ISSN 1978-2993. (Published) http://dx.doi.org/10.9767/bcrec.11.2.551.200-209 doi: 10.9767/bcrec.11.2.551.200-209
institution Universiti Malaysia Pahang Al-Sultan Abdullah
building UMPSA Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
url_provider http://umpir.ump.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Nur Nabillah, Mohd Arif
Vo, Dai-Viet N.
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
description Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out us-ing Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gra-vimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallin-ity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET.
format Article
author Nur Nabillah, Mohd Arif
Vo, Dai-Viet N.
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
author_facet Nur Nabillah, Mohd Arif
Vo, Dai-Viet N.
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
author_sort Nur Nabillah, Mohd Arif
title Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_short Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_full Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_fullStr Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_full_unstemmed Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
title_sort carbon dioxide dry reforming of glycerol for hydrogen production using ni/zro2 and ni/cao as catalysts
publisher Department of Chemical Engineering, Diponegoro University
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/17403/1/fkksa-2016-sumaiya-Carbon%20Dioxide%20Dry%20Reforming%20of%20Glycerol%20for%20Hydrogen.pdf
http://umpir.ump.edu.my/id/eprint/17403/
http://dx.doi.org/10.9767/bcrec.11.2.551.200-209
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