Synthetic CaO-based sorbent for high-temperature CO2 capture in sorption-enhanced hydrogen production

• Main Authors: Pecharaumporn, Piya, Wongsakulphasatch, Suwimol, Glinrun, Thongchai, Maneedaeng, Atthaphon, Zulkafli, Hassan, Assabumrungrat, Suttichai
• Format: Article
• Language: English; English
• Published: Elsevier 2019
• Subjects: TP Chemical technology
• Online Access: http://umpir.ump.edu.my/id/eprint/30310/1/Synthetic%20CaO-based%20sorbent%20for%20high-temperature%20CO2.pdf; http://umpir.ump.edu.my/id/eprint/30310/2/Synthetic%20CaO-based%20sorbent%20for%20high-temperature%20CO2_FULL.pdf; http://umpir.ump.edu.my/id/eprint/30310/; https://doi.org/10.1016/j.ijhydene.2018.06.153; https://doi.org/10.1016/j.ijhydene.2018.06.153
• Institution: Universiti Malaysia Pahang

Calcium precursor and surfactant addition on properties of synthetic alumina-containing CaO-based for CO2 capture and for sorption-enhanced steam methane reforming process (SE-SMR) were investigated. Results showed that the sorbent derived from calcium D-gluconic acid (CG-AN) offered CO2 sorption capacity of 0.38 g CO2/g sorbent, which is greater than 0.17 g CO2/g sorbent of the sorbent derived from calcium nitrate (CN-AN). Addition of CTAB surfactant during synthesis was found to enhance CO2 sorption capacity for CG-AN but not for CN-AN sorbents. Stability tests of the modified sorbents for 10 cycles showed that CG-AN-CTAB provided higher CO2 sorption capacity than CN-AN-CTAB for each corresponding cycle. Incorporation of CG-AN with Ni catalyst (Ni-CG-AN) using wet-mixing technique offered the longest pre-breakthrough period of 60 min for average maximum H2 purity of 88% at 600 °C and a steam/methane molar ratio of 3.