Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process
Link to publisher's homepage at http://www.myiem.org.my/
Saved in:
| Main Authors: | , , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
The Institution of Engineers, Malaysia
2011
|
| Subjects: | |
| Online Access: | http://dspace.unimap.edu.my/xmlui/handle/123456789/13742 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Universiti Malaysia Perlis |
| Language: | English |
| id |
my.unimap-13742 |
|---|---|
| record_format |
dspace |
| spelling |
my.unimap-137422011-09-14T08:43:46Z Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process Sugeng, Triwahyono Aishah, A. Jalil Hadi, Nur Halimaton, Hamdan Kobayashi, Masayoshi sugeng@ibnusina.utm.my CFR Cs-Ag/MPG membrane reactor Epoxidation of propylene Link to publisher's homepage at http://www.myiem.org.my/ The epoxidation of propylene to propylene oxide in a heterogeneous system was studied by using a Micro Porous Glass (MPG) membrane reactor immobilised with cesium-silver (Cs-Ag) catalysts. For a quantitative evaluation of the membrane re a c t o r efficiency to produce a propylene oxide, three different reactor systems were compared by using a diffusion flow reactor (DFR), convection flow reactor (CFR) and plug flow reactor (PFR). The selectivity of propylene oxide for DFR, CFR, and PFR were evaluated as 1-18 %, 12-14 %, and 1.5-4 % respectively at 423-523 K, and the CFR was observed to be the most suitable re a c t o r for epoxidation of propylene to propylene oxide because of a reaction stability. The steady state rate analysis of CFR consistently p roposed the Langmuir-Hinshelwood model equation based on two different active sites adsorption for the synthesis of pro p y l e n e oxide and a competitive adsorption on a single active site for the synthesis of carbon dioxide. At 503 K, the selectivity of p ropylene oxide was widely shifted from 11.2-17.5 % depending on the total reactant flow rate in the membrane pores, as flow rate is 50-150 cm3/min, indicating the convection flow in the pore to contribute to a selective growth of propylene oxide. 2011-09-14T08:43:46Z 2011-09-14T08:43:46Z 2006-09 Article The Journal of the Institution of Engineers, Malaysia, vol. 67(3), 2006, pages 7-12 0126-513X http://www.myiem.org.my/content/iem_journal_2006-177.aspx http://hdl.handle.net/123456789/13742 en The Institution of Engineers, Malaysia |
| institution |
Universiti Malaysia Perlis |
| building |
UniMAP Library |
| collection |
Institutional Repository |
| continent |
Asia |
| country |
Malaysia |
| content_provider |
Universiti Malaysia Perlis |
| content_source |
UniMAP Library Digital Repository |
| url_provider |
http://dspace.unimap.edu.my/ |
| language |
English |
| topic |
CFR Cs-Ag/MPG membrane reactor Epoxidation of propylene |
| spellingShingle |
CFR Cs-Ag/MPG membrane reactor Epoxidation of propylene Sugeng, Triwahyono Aishah, A. Jalil Hadi, Nur Halimaton, Hamdan Kobayashi, Masayoshi Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process |
| description |
Link to publisher's homepage at http://www.myiem.org.my/ |
| author2 |
sugeng@ibnusina.utm.my |
| author_facet |
sugeng@ibnusina.utm.my Sugeng, Triwahyono Aishah, A. Jalil Hadi, Nur Halimaton, Hamdan Kobayashi, Masayoshi |
| format |
Article |
| author |
Sugeng, Triwahyono Aishah, A. Jalil Hadi, Nur Halimaton, Hamdan Kobayashi, Masayoshi |
| author_sort |
Sugeng, Triwahyono |
| title |
Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process |
| title_short |
Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process |
| title_full |
Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process |
| title_fullStr |
Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process |
| title_full_unstemmed |
Development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process |
| title_sort |
development of membrane reactor for epoxidation of propylene to propylene oxide in a single step process |
| publisher |
The Institution of Engineers, Malaysia |
| publishDate |
2011 |
| url |
http://dspace.unimap.edu.my/xmlui/handle/123456789/13742 |
| _version_ |
1643790924511182848 |