Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment
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2014
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my.unimap-354002017-11-29T09:10:42Z Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment Ali Hussain, Reshak, Prof. Dr. Chen, Xuean Auluck, Sushil Kamarudin, Hussin, Brig. Jen. Dato' Prof. Dr. Chysky, Jan Wojciechowski, Artur Kityk, Ivan V. maalidph@yahoo.co.uk sauluck@gmail.com kamarudin@unimap.edu.my jan.Chysky@fs.cvut.cz awojciech2013@wp.pl ikityk@el.pcz.czest.pl Hyper-polarizability Linear optical properties Nonlinear optical susceptibilities Second-order nonlinear optical Single crystal x-ray diffraction Link to publisher's homepage at http://pubs.acs.org/ The single-crystal borate LiBaB9O15 was synthesized by a high-temperature solution reaction and structurally determined by the single-crystal X-ray diffraction technique. It crystallizes in the noncentrosymmetric space group R3c and features a three-dimensional ∞ 3[B9O15]3- anionic framework, with infinite channels in which the Li+ and Ba 2+ cations are located. The linear optical properties were investigated experimentally in terms of the absorption spectrum, which reveals an optical gap of 5.17 eV. In addition we have calculated the linear optical properties using state-of-the-art all-electron full potential linearized augmented plane wave method. The nonlinear optical susceptibilities, namely, the second harmonic generation and the hyperpolarizability of the single-crystal borate LiBaB9O15 are calculated and evaluated at a static limit and at λ = 1064 nm. The calculation shows there exists three second-order nonlinear optical susceptiblities tensors components. We present measurements of the IR spectra in the range 500-2000 cm-1, and the second harmonic generation was performed using a Quantel 15 ns Nd:YAG laser operating at 1064 nm. 2014-06-11T14:46:48Z 2014-06-11T14:46:48Z 2013-11 Article Journal of Physical Chemistry B, vol. 117(45), 2013, pages 14141-14150 1520-6106 (Print) 1520-5207 (Online) http://pubs.acs.org/doi/abs/10.1021/jp4077905 http://dspace.unimap.edu.my:80/dspace/handle/123456789/35400 10.1021/jp4077905 en American Chemical Society |
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Hyper-polarizability Linear optical properties Nonlinear optical susceptibilities Second-order nonlinear optical Single crystal x-ray diffraction |
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Hyper-polarizability Linear optical properties Nonlinear optical susceptibilities Second-order nonlinear optical Single crystal x-ray diffraction Ali Hussain, Reshak, Prof. Dr. Chen, Xuean Auluck, Sushil Kamarudin, Hussin, Brig. Jen. Dato' Prof. Dr. Chysky, Jan Wojciechowski, Artur Kityk, Ivan V. Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment |
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Link to publisher's homepage at http://pubs.acs.org/ |
| author2 |
maalidph@yahoo.co.uk |
| author_facet |
maalidph@yahoo.co.uk Ali Hussain, Reshak, Prof. Dr. Chen, Xuean Auluck, Sushil Kamarudin, Hussin, Brig. Jen. Dato' Prof. Dr. Chysky, Jan Wojciechowski, Artur Kityk, Ivan V. |
| format |
Article |
| author |
Ali Hussain, Reshak, Prof. Dr. Chen, Xuean Auluck, Sushil Kamarudin, Hussin, Brig. Jen. Dato' Prof. Dr. Chysky, Jan Wojciechowski, Artur Kityk, Ivan V. |
| author_sort |
Ali Hussain, Reshak, Prof. Dr. |
| title |
Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment |
| title_short |
Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment |
| title_full |
Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment |
| title_fullStr |
Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment |
| title_full_unstemmed |
Linear and nonlinear optical susceptibilities and the hyperpolarizability of borate LiBaB9O15 single-crystal: theory and experiment |
| title_sort |
linear and nonlinear optical susceptibilities and the hyperpolarizability of borate libab9o15 single-crystal: theory and experiment |
| publisher |
American Chemical Society |
| publishDate |
2014 |
| url |
http://dspace.unimap.edu.my:80/dspace/handle/123456789/35400 |
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1643802758915031040 |