The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands
Ru(II) complexes with diazabutadiene (R-DAB) ligands have been prepared. The reaction of RuCl3·nH2O with P(p-tolyl)3 gave a [RuCl2{P(p-tolyl)3}] precursor, whose reactions with R-DAB in toluene gave dinuclear trichloro-bridged Ru(II) complexes [Ru2Cl3(P(p-tolyl)3)2(R-DAB)2](BF4) which have been char...
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my.unimas.ir.235002021-04-28T13:11:13Z http://ir.unimas.my/id/eprint/23500/ The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands Tay, Meng Guan Chia, Ying Ying Hui, Suzie Chin Kuan Pan, Tze Pei Q Science (General) QD Chemistry Ru(II) complexes with diazabutadiene (R-DAB) ligands have been prepared. The reaction of RuCl3·nH2O with P(p-tolyl)3 gave a [RuCl2{P(p-tolyl)3}] precursor, whose reactions with R-DAB in toluene gave dinuclear trichloro-bridged Ru(II) complexes [Ru2Cl3(P(p-tolyl)3)2(R-DAB)2](BF4) which have been characterized by spectroscopic methods. In addition, one of the complexes was characterized using X-ray crystallography. Meanwhile, two mononuclear Ru(II) complexes [RuCl2(P(p-tolyl)3)2(R-DAB)] were obtained from the reactions of the [RuCl2{P(p-tolyl)3}] precursor with R-DAB ligands in THF. The two trans-mononuclear complexes were characterized by X-ray crystallography and solid-state 31P NMR. A temperature-dependent 31P NMR study was carried out to monitor the formation of dinuclear and mononuclear complexes. Springer Nature 2019 Article PeerReviewed text en http://ir.unimas.my/id/eprint/23500/1/Ying.pdf Tay, Meng Guan and Chia, Ying Ying and Hui, Suzie Chin Kuan and Pan, Tze Pei (2019) The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands. Transition Metal Chemistry, 44 (3). pp. 293-301. ISSN 1572-901X https://link.springer.com/article/10.1007/s11243-018-00293-0 DOI:org/10.1007/s11243-018-00293-0) |
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Q Science (General) QD Chemistry Tay, Meng Guan Chia, Ying Ying Hui, Suzie Chin Kuan Pan, Tze Pei The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands |
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Ru(II) complexes with diazabutadiene (R-DAB) ligands have been prepared. The reaction of RuCl3·nH2O with P(p-tolyl)3 gave a [RuCl2{P(p-tolyl)3}] precursor, whose reactions with R-DAB in toluene gave dinuclear trichloro-bridged Ru(II) complexes [Ru2Cl3(P(p-tolyl)3)2(R-DAB)2](BF4) which have been characterized by spectroscopic methods. In addition, one of the complexes was characterized using X-ray crystallography. Meanwhile, two mononuclear Ru(II) complexes [RuCl2(P(p-tolyl)3)2(R-DAB)] were obtained from the reactions of the [RuCl2{P(p-tolyl)3}] precursor with R-DAB ligands in THF. The two trans-mononuclear complexes were characterized by X-ray crystallography and solid-state 31P NMR. A temperature-dependent 31P NMR study was carried out to monitor the formation of dinuclear and mononuclear complexes. |
format |
Article |
author |
Tay, Meng Guan Chia, Ying Ying Hui, Suzie Chin Kuan Pan, Tze Pei |
author_facet |
Tay, Meng Guan Chia, Ying Ying Hui, Suzie Chin Kuan Pan, Tze Pei |
author_sort |
Tay, Meng Guan |
title |
The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions
of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands |
title_short |
The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions
of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands |
title_full |
The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions
of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands |
title_fullStr |
The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions
of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands |
title_full_unstemmed |
The formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions
of dichlorotris(p‑tolylphosphine)ruthenium(II) with diazabutadiene ligands |
title_sort |
formation of dinuclear trichloro‑bridged and mononuclear ruthenium complexes from the reactions
of dichlorotris(p‑tolylphosphine)ruthenium(ii) with diazabutadiene ligands |
publisher |
Springer Nature |
publishDate |
2019 |
url |
http://ir.unimas.my/id/eprint/23500/1/Ying.pdf http://ir.unimas.my/id/eprint/23500/ https://link.springer.com/article/10.1007/s11243-018-00293-0 |
_version_ |
1698700785775280128 |