Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review
Biodiesel; Carbonation; Irradiation; Microwave irradiation; Reaction kinetics; Alternative materials; Biodiesel production; Biomass resources; Crude glycerol; Dimethyl carbonate; Glycerol carbonate; Organic carbonates; Production methods; Glycerol
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2023
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my.uniten.dspace-257462023-05-29T16:13:43Z Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review Nomanbhay S. Ong M.Y. Chew K.W. Show P.-L. Lam M.K. Chen W.-H. 22135844300 57191970824 57192980692 47861451300 57194113699 57200873137 Biodiesel; Carbonation; Irradiation; Microwave irradiation; Reaction kinetics; Alternative materials; Biodiesel production; Biomass resources; Crude glycerol; Dimethyl carbonate; Glycerol carbonate; Organic carbonates; Production methods; Glycerol As a promising alternative renewable liquid fuel, biodiesel production has increased and eventually led to an increase in the production of its by-product, crude glycerol. The vast generation of glycerol has surpassed the market demand. Hence, the crude glycerol produced should be utilized effectively to increase the viability of biodiesel production. One of them is through crude glycerol upgrading, which is not economical. A good deal of attention has been dedicated to research for alternative material and chemicals derived from sustainable biomass resources. It will be more valuable if the crude glycerol is converted into glycerol derivatives, and so, increase the economic possibility of the biodiesel production. Studies showed that glycerol carbonate plays an important role, as a building block, in synthesizing the glycerol oligomers at milder conditions under microwave irradiation. This review presents a brief outline of the physio-chemical, thermodynamic, toxicological, production methods, reactivity, and application of organic carbonates derived from glycerol with a major focus on glycerol carbonate and dimethyl carbonate (DMC), as a green chemical, for application in the chemical and biotechnical field. Research gaps and further improvements have also been discussed. � 2020 by the authors. Final 2023-05-29T08:13:43Z 2023-05-29T08:13:43Z 2020 Review 10.3390/en13061483 2-s2.0-85082663918 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85082663918&doi=10.3390%2fen13061483&partnerID=40&md5=fff4b73e3bb6802b10d72f604f716b90 https://irepository.uniten.edu.my/handle/123456789/25746 13 6 1483 All Open Access, Gold, Green MDPI AG Scopus |
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| description |
Biodiesel; Carbonation; Irradiation; Microwave irradiation; Reaction kinetics; Alternative materials; Biodiesel production; Biomass resources; Crude glycerol; Dimethyl carbonate; Glycerol carbonate; Organic carbonates; Production methods; Glycerol |
| author2 |
22135844300 |
| author_facet |
22135844300 Nomanbhay S. Ong M.Y. Chew K.W. Show P.-L. Lam M.K. Chen W.-H. |
| format |
Review |
| author |
Nomanbhay S. Ong M.Y. Chew K.W. Show P.-L. Lam M.K. Chen W.-H. |
| spellingShingle |
Nomanbhay S. Ong M.Y. Chew K.W. Show P.-L. Lam M.K. Chen W.-H. Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review |
| author_sort |
Nomanbhay S. |
| title |
Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review |
| title_short |
Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review |
| title_full |
Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review |
| title_fullStr |
Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review |
| title_full_unstemmed |
Organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: A review |
| title_sort |
organic carbonate production utilizing crude glycerol derived as by-product of biodiesel production: a review |
| publisher |
MDPI AG |
| publishDate |
2023 |
| _version_ |
1806425594461683712 |