Adsorptive Removal of Boron by DIAION� CRB05: Characterization, Kinetics, Isotherm, and Optimization by Response Surface Methodology

• Main Authors: Al-dhawi B.N.S., Kutty S.R.M., Hayder G., Elnaim B.M.E., Mnzool M., Noor A., Saeed A.A.H., Al-Mahbashi N.M.Y., Al-Nini A., Jagaba A.H.
• Other Authors: 57219253320
• Format: Article
• Published: Multidisciplinary Digital Publishing Institute (MDPI) 2024
• Subjects: adsorption; boron; DIAION CRB05 resin; kinetic studies; response surface methodology; Boric acid; Boride coatings; Boron; Chemicals removal (water treatment); Chromium compounds; Cost effectiveness; Field emission microscopes; Isotherms; Kinetics; Resins; Scanning electron microscopy; Surface properties; Adsorptive removal; Batch experiments; Dynamic experiment; Kinetic isotherms; Kinetic study; Optimisations; Response surfaces methods; Response-surface methodology; Waters resources; Adsorption
• Institution: Universiti Tenaga Nasional

A significant issue for the ecosystem is the presence of boron in water resources, particularly in produced water. Batch and dynamic experiments were used in this research to extract boron in the form of boric acid from aqueous solutions using boron selective resins, DIAION CRB05. DIAION� CRB05 is an adsorbent that is effective in extracting boron from aqueous solutions due to its high binding capacity and selectivity for boron ions, and it is also regenerable, making it cost-effective and sustainable. Field Emission Scanning Electron Microscopy (FESEM), X-ray diffraction (XRD), and FTIR analysis for DIAION CRB05 characterization. To increase the adsorption capacity and find the ideal values for predictor variables such as pH, adsorbent dose, time, and boric acid concentration, the Box�Behnken response surface method (RSM) was applied. The dosage was reported to be 2000 mg/L at pH 2 and boron initial concentration of 1115 mg/L with 255 min for the highest removal anticipated from RSM. According to the outcomes of this research, the DIAION CRB05 material enhanced boron removal capability and has superior performance to several currently available adsorbents, which makes it suitable for use as an adsorbent for removing boric acid from aqueous solutions. The outcomes of isotherm and kinetic experiments were fitted using linear methods. The Temkin isotherm and the pseudo-first-order model were found to have good fits after comparison with R2 of 0.998, and 0.997, respectively. The results of the study demonstrate the effectiveness of DIAION� CRB05 in removing boron from aqueous solutions and provide insight into the optimal conditions for the adsorption process. Thus, the DIAION CRB05 resin was chosen as the ideal choice for recovering boron from an aqueous solution because of its higher sorption capacity and percentage of boron absorbed. � 2023 by the authors.