Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions

Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions

This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Cr...

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Bibliographic Details
Main Authors: Loghmani-Khouzani, H., Tamjidi, P., Mohammadpoor-Baltork, I., Yaeghoobi, M., Rahman, N.A., Khosropour, A.R., Moghadam, M., Tangestaninejad, S., Mirkhani, V., Habibi, M.H., Kashima, A., Suzuki, T.
Format: Article
Language:English
Published: 2017
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Institution: Universiti Tenaga Nasional
Language: English
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Summary:This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system. © 2013 HeteroCorporation.

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