Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz
A dielectric spectroscopy method was applied to determine major fatty acids composition in vegetable oils. Dielectric constants of vegetable oils were measured in the frequency range of 5–30 MHz. After data pre-treatment, prediction models were constructed using partial least squares (PLS) regressio...
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my.upm.eprints.1001992024-07-15T06:16:45Z http://psasir.upm.edu.my/id/eprint/100199/ Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz Amat Sairin, Masyitah Abd Aziz, Samsuzana Chan, Yoke Mun Khaled, Alfadhl Yahya Rokhani, Fakhrul Zaman A dielectric spectroscopy method was applied to determine major fatty acids composition in vegetable oils. Dielectric constants of vegetable oils were measured in the frequency range of 5–30 MHz. After data pre-treatment, prediction models were constructed using partial least squares (PLS) regression between dielectric spectral values and the fatty acids compositions measured by gas chromatography. Generally, the root means square error of validation (RMSECV) was less than 11.23% in the prediction of individual fatty acids. The determination coefficient (R2) between predicted and measured oleic, linoleic, mono-unsaturated, and poly-unsaturated fatty acids were 0.84, 0.77, 0.84, and 0.84, respectively. These results indicated that dielectric spectroscopy coupled with PLS regression could be a promising method for predicting major fatty acid composition in vegetable oils and has the potential to be used for in-situ monitoring systems of daily consumption of dietary fatty acids. Public Library of Science 2022-05-26 Article PeerReviewed Amat Sairin, Masyitah and Abd Aziz, Samsuzana and Chan, Yoke Mun and Khaled, Alfadhl Yahya and Rokhani, Fakhrul Zaman (2022) Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz. PLOS One, 17 (5). art. no. 268827. pp. 1-14. ISSN 1932-6203 https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0268827 10.1371/journal.pone.0268827 |
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A dielectric spectroscopy method was applied to determine major fatty acids composition in vegetable oils. Dielectric constants of vegetable oils were measured in the frequency range of 5–30 MHz. After data pre-treatment, prediction models were constructed using partial least squares (PLS) regression between dielectric spectral values and the fatty acids compositions measured by gas chromatography. Generally, the root means square error of validation (RMSECV) was less than 11.23% in the prediction of individual fatty acids. The determination coefficient (R2) between predicted and measured oleic, linoleic, mono-unsaturated, and poly-unsaturated fatty acids were 0.84, 0.77, 0.84, and 0.84, respectively. These results indicated that dielectric spectroscopy coupled with PLS regression could be a promising method for predicting major fatty acid composition in vegetable oils and has the potential to be used for in-situ monitoring systems of daily consumption of dietary fatty acids. |
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Article |
author |
Amat Sairin, Masyitah Abd Aziz, Samsuzana Chan, Yoke Mun Khaled, Alfadhl Yahya Rokhani, Fakhrul Zaman |
spellingShingle |
Amat Sairin, Masyitah Abd Aziz, Samsuzana Chan, Yoke Mun Khaled, Alfadhl Yahya Rokhani, Fakhrul Zaman Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz |
author_facet |
Amat Sairin, Masyitah Abd Aziz, Samsuzana Chan, Yoke Mun Khaled, Alfadhl Yahya Rokhani, Fakhrul Zaman |
author_sort |
Amat Sairin, Masyitah |
title |
Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz |
title_short |
Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz |
title_full |
Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz |
title_fullStr |
Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz |
title_full_unstemmed |
Analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 MHz |
title_sort |
analysis and prediction of the major fatty acids in vegetable oils using dielectric spectroscopy at 5–30 mhz |
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Public Library of Science |
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2022 |
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http://psasir.upm.edu.my/id/eprint/100199/ https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0268827 |
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