Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)

Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)

Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa...

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Main Authors: Alzaalouk, Amna Salem, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Ng, Seik Weng, Tiekink, Edward Richard Tom
Format: Article
Language:English
Published: International Union of Crystallography 2010
Online Access:http://psasir.upm.edu.my/id/eprint/13428/1/Bis%20%28N-sec-butyl-N%29.pdf
http://psasir.upm.edu.my/id/eprint/13428/
http://scripts.iucr.org/cgi-bin/paper?bt5329
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Institution: Universiti Putra Malaysia
Language: English
id my.upm.eprints.13428
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spelling my.upm.eprints.134282015-10-22T06:29:42Z http://psasir.upm.edu.my/id/eprint/13428/ Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II) Alzaalouk, Amna Salem Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Ng, Seik Weng Tiekink, Edward Richard Tom Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5). International Union of Crystallography 2010-09-01 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/13428/1/Bis%20%28N-sec-butyl-N%29.pdf Alzaalouk, Amna Salem and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Ng, Seik Weng and Tiekink, Edward Richard Tom (2010) Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (pt. 9). m1165-m1166. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?bt5329 10.1107/S160053681003367
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S inter-actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5).
format Article
author Alzaalouk, Amna Salem
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Ng, Seik Weng
Tiekink, Edward Richard Tom
spellingShingle Alzaalouk, Amna Salem
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Ng, Seik Weng
Tiekink, Edward Richard Tom
Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)
author_facet Alzaalouk, Amna Salem
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Ng, Seik Weng
Tiekink, Edward Richard Tom
author_sort Alzaalouk, Amna Salem
title Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)
title_short Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)
title_full Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)
title_fullStr Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)
title_full_unstemmed Bis(N-sec-butyl-N-n-propyldithiocarbamato- 2S,S')(1,10-phenanthroline- 2N,N')zinc(II)
title_sort bis(n-sec-butyl-n-n-propyldithiocarbamato- 2s,s')(1,10-phenanthroline- 2n,n')zinc(ii)
publisher International Union of Crystallography
publishDate 2010
url http://psasir.upm.edu.my/id/eprint/13428/1/Bis%20%28N-sec-butyl-N%29.pdf
http://psasir.upm.edu.my/id/eprint/13428/
http://scripts.iucr.org/cgi-bin/paper?bt5329
_version_ 1643825328883236864

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