Dimethylsulphoxide Complexes of Vanadium(III)

Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead...

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Main Authors:	Sirat, Kamaliah, W.Smith, Peter
Format:	Article
Language:	English English
Published:	1992
Online Access:	http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf http://psasir.upm.edu.my/id/eprint/2939/
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Institution:	Universiti Putra Malaysia
Language:	English English

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spelling	my.upm.eprints.29392013-05-27T07:04:35Z http://psasir.upm.edu.my/id/eprint/2939/ Dimethylsulphoxide Complexes of Vanadium(III) Sirat, Kamaliah W.Smith, Peter Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively 1992 Article NonPeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf Sirat, Kamaliah and W.Smith, Peter (1992) Dimethylsulphoxide Complexes of Vanadium(III). Pertanika, 15 (2). pp. 137-142. English
institution	Universiti Putra Malaysia
building	UPM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Putra Malaysia
content_source	UPM Institutional Repository
url_provider	http://psasir.upm.edu.my/
language	English English
description	Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively
format	Article
author	Sirat, Kamaliah W.Smith, Peter
spellingShingle	Sirat, Kamaliah W.Smith, Peter Dimethylsulphoxide Complexes of Vanadium(III)
author_facet	Sirat, Kamaliah W.Smith, Peter
author_sort	Sirat, Kamaliah
title	Dimethylsulphoxide Complexes of Vanadium(III)
title_short	Dimethylsulphoxide Complexes of Vanadium(III)
title_full	Dimethylsulphoxide Complexes of Vanadium(III)
title_fullStr	Dimethylsulphoxide Complexes of Vanadium(III)
title_full_unstemmed	Dimethylsulphoxide Complexes of Vanadium(III)
title_sort	dimethylsulphoxide complexes of vanadium(iii)
publishDate	1992
url	http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf http://psasir.upm.edu.my/id/eprint/2939/
_version_	1643822465954086912

Dimethylsulphoxide Complexes of Vanadium(III)

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