2,2-Dibenzylhydrazin-1-ium chloride
In the title salt, C14H17N2 +·Cl-, the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N - H⋯Cl hydrogen bonds, which lead to a supramolecular undulating ribbo...
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International Union of Crystallography
2013
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| Online Access: | http://psasir.upm.edu.my/id/eprint/30097/1/2%2C2-Dibenzylhydrazin-1-ium%20chloride.pdf http://psasir.upm.edu.my/id/eprint/30097/ |
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my.upm.eprints.300972015-12-29T03:12:52Z http://psasir.upm.edu.my/id/eprint/30097/ 2,2-Dibenzylhydrazin-1-ium chloride Tayamon, Shahedeh S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. In the title salt, C14H17N2 +·Cl-, the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N - H⋯Cl hydrogen bonds, which lead to a supramolecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}2 synthons. The chains are connected into layers in the ab plane by C - H⋯π interactions. International Union of Crystallography 2013 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/30097/1/2%2C2-Dibenzylhydrazin-1-ium%20chloride.pdf Tayamon, Shahedeh and S. A. Ravoof, Thahira Begum and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne and Tiekink, Edward R. T. (2013) 2,2-Dibenzylhydrazin-1-ium chloride. Acta Crystallographica Section E: Structure Reports Online, 69 (pt.3). o382. ISSN 1600-5368 10.1107/S1600536813003966 English |
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In the title salt, C14H17N2 +·Cl-, the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N - H⋯Cl hydrogen bonds, which lead to a supramolecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}2 synthons. The chains are connected into layers in the ab plane by C - H⋯π interactions. |
| format |
Article |
| author |
Tayamon, Shahedeh S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. |
| spellingShingle |
Tayamon, Shahedeh S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. 2,2-Dibenzylhydrazin-1-ium chloride |
| author_facet |
Tayamon, Shahedeh S. A. Ravoof, Thahira Begum Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Tiekink, Edward R. T. |
| author_sort |
Tayamon, Shahedeh |
| title |
2,2-Dibenzylhydrazin-1-ium chloride |
| title_short |
2,2-Dibenzylhydrazin-1-ium chloride |
| title_full |
2,2-Dibenzylhydrazin-1-ium chloride |
| title_fullStr |
2,2-Dibenzylhydrazin-1-ium chloride |
| title_full_unstemmed |
2,2-Dibenzylhydrazin-1-ium chloride |
| title_sort |
2,2-dibenzylhydrazin-1-ium chloride |
| publisher |
International Union of Crystallography |
| publishDate |
2013 |
| url |
http://psasir.upm.edu.my/id/eprint/30097/1/2%2C2-Dibenzylhydrazin-1-ium%20chloride.pdf http://psasir.upm.edu.my/id/eprint/30097/ |
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