Thermoluminescence characteristics of copper activated calcium borate nanocrystals (CaB4O7:Cu)

The copper activated calcium tetraborate (CaB4O7:Cu) nanophosphor was synthesized by a combination of facile co-precipitation and thermal treatment methods for the first time. Thermoluminescence and dosimetric characteristics of the gamma irradiated CaB4O7:Cu nanophosphor was reported. The glow curv...

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Bibliographic Details
Main Authors: Haghiri, Maryam Erfani, Saion, Elias, Soltani, Nayereh, Wan Abdullah, Wan Saffiey, Navasery, Manizheh, Hashim, Mansor
Format: Article
Language:English
Published: Elsevier 2013
Online Access:http://psasir.upm.edu.my/id/eprint/30408/1/Thermoluminescence%20characteristics%20of%20copper%20activated%20calcium%20borate%20nanocrystals.pdf
http://psasir.upm.edu.my/id/eprint/30408/
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Institution: Universiti Putra Malaysia
Language: English
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Summary:The copper activated calcium tetraborate (CaB4O7:Cu) nanophosphor was synthesized by a combination of facile co-precipitation and thermal treatment methods for the first time. Thermoluminescence and dosimetric characteristics of the gamma irradiated CaB4O7:Cu nanophosphor was reported. The glow curves shows two well resolved TL peaks centered at about 120 °C and 260 °C. The copper concentration was varied from 1 to 3 mol% and it was found that the nanocrystalline CaB4O7:Cu with a dopant concentration of 2 mol% has the highest sensitivity among the other dopant concentrations. The results demonstrated that copper can enhance TL efficiency to 2.26 times more than that of un-doped nanocrystalline samples. Moreover, the dose response of the dosimetric peak at 260 °C follows a good linearity up to 3 kGy whereas the linearity of lower temperature peak at 120 °C extended up to 30 Gy. The linearity characteristic of the present nanophosphor suggests it as a candidate towards dosimetric applications.