Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method
Various normal lower ammines and high-energy modifications of the lower ammines of cobalt(II) sulfate and nickel(II) sulfate have been prepared and the heats of solution in dilute ammonia have been measured for both types. For each of these ammine systems the maximum difference in heat of solution,...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
N R C Research Press
1970
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/33881/1/15.%2033881%20ligand%20field%20splitting.pdf http://psasir.upm.edu.my/id/eprint/33881/ http://www.nrcresearchpress.com/doi/abs/10.1139/v70-364#.VTZyDCGeDGc |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Universiti Putra Malaysia |
| Language: | English |
| id |
my.upm.eprints.33881 |
|---|---|
| record_format |
eprints |
| spelling |
my.upm.eprints.338812015-04-21T06:02:33Z http://psasir.upm.edu.my/id/eprint/33881/ Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method Muhammmad, Badri Jamieson, J. W. S. Various normal lower ammines and high-energy modifications of the lower ammines of cobalt(II) sulfate and nickel(II) sulfate have been prepared and the heats of solution in dilute ammonia have been measured for both types. For each of these ammine systems the maximum difference in heat of solution, expressed as kcal/rnole of each heptaammine, between the high-energy and the normal salts has been found to be in close agreement with the ligand field splitting energy of the hexaamminemetal(lI) ion. N R C Research Press 1970 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/33881/1/15.%2033881%20ligand%20field%20splitting.pdf Muhammmad, Badri and Jamieson, J. W. S. (1970) Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method. Canadian Journal of Chemistry, 48 (14). pp. 2177-2181. ISSN 0008-4042; ESSN: 1480-3291 http://www.nrcresearchpress.com/doi/abs/10.1139/v70-364#.VTZyDCGeDGc |
| institution |
Universiti Putra Malaysia |
| building |
UPM Library |
| collection |
Institutional Repository |
| continent |
Asia |
| country |
Malaysia |
| content_provider |
Universiti Putra Malaysia |
| content_source |
UPM Institutional Repository |
| url_provider |
http://psasir.upm.edu.my/ |
| language |
English |
| description |
Various normal lower ammines and high-energy modifications of the lower ammines of cobalt(II) sulfate and nickel(II) sulfate have been prepared and the heats of solution in dilute ammonia have been measured for both types. For each of these ammine systems the maximum difference in heat of solution, expressed as kcal/rnole of each heptaammine, between the high-energy and the normal salts has been found to be in close agreement with the ligand field splitting energy of the hexaamminemetal(lI) ion. |
| format |
Article |
| author |
Muhammmad, Badri Jamieson, J. W. S. |
| spellingShingle |
Muhammmad, Badri Jamieson, J. W. S. Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method |
| author_facet |
Muhammmad, Badri Jamieson, J. W. S. |
| author_sort |
Muhammmad, Badri |
| title |
Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method |
| title_short |
Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method |
| title_full |
Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method |
| title_fullStr |
Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method |
| title_full_unstemmed |
Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method |
| title_sort |
ligand field splitting energies of the hexaamminecobalt(ii) ion and the hexaamminenickel(ii) ion measured by a calorimetric method |
| publisher |
N R C Research Press |
| publishDate |
1970 |
| url |
http://psasir.upm.edu.my/id/eprint/33881/1/15.%2033881%20ligand%20field%20splitting.pdf http://psasir.upm.edu.my/id/eprint/33881/ http://www.nrcresearchpress.com/doi/abs/10.1139/v70-364#.VTZyDCGeDGc |
| _version_ |
1643830997088731136 |