Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II)

• Main Authors: Bahron, Hadariah, Mohd Tajuddin, Amalina, Wan Ibrahim, Wan Nazihah, Fun, Hoong Kun, Chantrapromma, Suchada
• Format: Article
• Language: English
• Published: International Union of Crystallography 2014
• Subjects: QC1-999 Physics
• Online Access: http://eprints.usm.my/38591/1/Crystal_structure_of_bis%7B2-%5B%28E%29-%284-methoxylbenzyl%29-.pdf; http://eprints.usm.my/38591/; https://doi.org/10.1107/S160053681401650X
• Institution: Universiti Sains Malaysia

The asymmetric unit of the title compound, [Ni(C15H14NO2)2], comprises an NiII cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The NiII cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) A ° , respectively. The plane of the methoxybenzene ring makes a dihedral angle of 84.92 (6)� with that of the phenolate ring. In the crystal, molecules are linked into screw chains by weak C—H� � �O hydrogen bonds. Additional C—H� � �O hydrogen bonds, together with C—H� � �� contacts, arrange the molecules into sheets parallel to the ac plane.