Fabrication, structure and properties of epoxy/metal nanocomposites

Gd2O3 nanoparticles surface-modified with IPDI were compounded with epoxy. IPDI provided an anchor into the porous Gd2O3 surface and a bridge into the matrix, thus creating strong bonds between matrix and Gd2O3. 1.7 vol.-% Gd2O3 increased the Young’s modulus of epoxy by 16–19%; the surface-modified Gd...

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Bibliographic Details
Main Authors: Ma, Jun, Bao La, Ly Truc, Zaman, Izzuddin, Meng, Qingshi, Luong, Lee, Ogilvie, Denise, Kuan, Hsu-Chiang
Format: Article
Language:English
Published: Wiley 2011
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Online Access:http://eprints.uthm.edu.my/4576/1/AJ%202017%20%28196%29%20Fabrication%2C%20structure%20and%20properties%20of%20epoxymetal%20nanocomposites.pdf
http://eprints.uthm.edu.my/4576/
http://dx.doi.org/10.1002/mame.201000409
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Institution: Universiti Tun Hussein Onn Malaysia
Language: English
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Summary:Gd2O3 nanoparticles surface-modified with IPDI were compounded with epoxy. IPDI provided an anchor into the porous Gd2O3 surface and a bridge into the matrix, thus creating strong bonds between matrix and Gd2O3. 1.7 vol.-% Gd2O3 increased the Young’s modulus of epoxy by 16–19%; the surface-modified Gd2O3 nanoparticles improved the critical strain energy release rate by 64.3% as compared to 26.4% produced by the unmodified nanoparticles. The X-ray shielding efficiency of neat epoxy was enhanced by 300–360%, independent of the interface modification. Interface debonding consumes energy and leads to crack pinning and matrix shear banding; most fracture energy is consumed by matrix shear banding as shown by the large number of ridges on the fracture surface.