Fabrication, structure and properties of epoxy/metal nanocomposites
Gd2O3 nanoparticles surface-modified with IPDI were compounded with epoxy. IPDI provided an anchor into the porous Gd2O3 surface and a bridge into the matrix, thus creating strong bonds between matrix and Gd2O3. 1.7 vol.-% Gd2O3 increased the Young’s modulus of epoxy by 16–19%; the surface-modified Gd...
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Main Authors: | , , , , , , |
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Format: | Article |
Language: | English |
Published: |
Wiley
2011
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Subjects: | |
Online Access: | http://eprints.uthm.edu.my/4576/1/AJ%202017%20%28196%29%20Fabrication%2C%20structure%20and%20properties%20of%20epoxymetal%20nanocomposites.pdf http://eprints.uthm.edu.my/4576/ http://dx.doi.org/10.1002/mame.201000409 |
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Institution: | Universiti Tun Hussein Onn Malaysia |
Language: | English |
Summary: | Gd2O3 nanoparticles surface-modified with IPDI were compounded with epoxy. IPDI provided an anchor into the porous Gd2O3 surface and a bridge into the matrix, thus creating strong bonds between matrix and Gd2O3. 1.7 vol.-% Gd2O3 increased the Young’s modulus of epoxy by 16–19%; the surface-modified Gd2O3 nanoparticles improved the critical strain energy release rate by 64.3% as compared to 26.4% produced by the unmodified nanoparticles. The X-ray shielding efficiency of neat epoxy was enhanced by 300–360%, independent of the interface modification. Interface debonding consumes energy and leads to crack pinning and matrix shear banding; most fracture energy is consumed by matrix shear banding as shown by the large number of ridges on the fracture surface. |
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