Conductivity and morphological characteristics of untreated and alkali treated natural fibre reinforced lldpe-nr polymer composite
Polymer nanocomposite has been actively explored in dielectric insulation studies due to its exceptional electrical properties exhibited by these materials. However, inferior properties of polymer biocomposite which is the hydrophilic properties causes less attention in dielectric insulation fiel...
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Format: | Thesis |
Language: | English English English |
Published: |
2022
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Online Access: | http://eprints.uthm.edu.my/8457/1/24p%20NISHANTHI%20SUNTHRASAKARAN.pdf http://eprints.uthm.edu.my/8457/2/NISHANTHI%20SUNTHRASAKARAN%20COPYRIGHT%20DECLARATION.pdf http://eprints.uthm.edu.my/8457/3/NISHANTHI%20SUNTHRASAKARAN%20WATERMARK.pdf http://eprints.uthm.edu.my/8457/ |
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Institution: | Universiti Tun Hussein Onn Malaysia |
Language: | English English English |
Summary: | Polymer nanocomposite has been actively explored in dielectric insulation studies due
to its exceptional electrical properties exhibited by these materials. However, inferior
properties of polymer biocomposite which is the hydrophilic properties causes less
attention in dielectric insulation field. Besides that, the natural fibre waste could be
used for a good cause that contributes to Sustainable Development Goals (SDG).
Hence, this research is aimed to study the polarization current, depolarization current
and conductivity of linear-low density polyethylene (LLDPE-NR) with three different
types of natural fibre as filler which are empty fruit bunch (EFB), oil palm frond (OPF)
and pineapple leaf fibre (PALF). The samples were fabricated with LLDPE-NR
(80:20) as the matrix and compatibilizer by varying the percentage of EFB, OPF and
PALF fibre (2.5%, 5%, 7.5% and 10%). The fibres were pre-treated for 6 hours with
5% of sodium hydroxide solution (NaOH) under room temperature. The sample were
then fabricated with treated and untreated fibres to assess the difference thoroughly.
Moisture absorption test (ASTM D570) was presented for degradation effect.
Morphological tests (FESEM, EDX and FTIR) were conducted to monitor the effect
of alkali treatment on the fibres and the physical structure of the polymer
biocomposite. Result obtained indicates that samples that consist of alkali treated EFB,
OPF and PALF exhibits lesser agglomeration compared to sample with untreated
fibres which indicates better adhesive properties. The conductivity of each sample was
measured using Polarization and Depolarization Current (PDC) testing values. Result
indicated 10% of treated OPF fibre is the optimum filler concentration with lowest
maximum conductivity value 48.76pS/m under normal condition. Whereas, 2.4% of
treated EFB fibre exhibits lowest maximum conductivity with 84.7pS/m under wet
condition. In general, treated OPF and EFB fibre performs better when incorporated
with LLDPE-NR by exhibiting lower electrical conductivity compared to PALF fibre |
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