Performance analysis of rGO-bridged g-C3N4/ZnV2O6 S-scheme heterojunction for CO2 photoreduction with H2O in an externally reflected photoreactor.

• Main Authors: Bafaqeer, Abdullah, Tahir, Muhammad, Saidina Amin, Nor Aishah, Ummer, Aniz Chennampilly, Thabit, Hammam Abdurabu, Dhamodharan, Duraisami, Ahmed, Shakeel, Kumar, Naveen
• Format: Article
• Published: Elsevier Ltd. 2023
• Subjects: QC Physics
• Online Access: http://eprints.utm.my/106218/; http://dx.doi.org/10.1016/j.jallcom.2023.171833
• Institution: Universiti Teknologi Malaysia

The photocatalytic conversion of CO2 with H2O over rGO-bridged g-C3N4/ZnV2O6 S-scheme heterojunction using an externally reflected photoreactor has been investigated. The structure and properties of photocatalysts, prepared via the one-pot solvothermal method, were characterized by XRD, RAMAN, FESEM, EDX, HRTEM, UV–vis and PL spectrophotometry. The 4 % rGO-bridged g-C3N4/ZnV2O6 (1:1) nanocomposite registered the highest CH3OH yield. The maximum yield of CH3OH over 4 % rGO-bridged g-C3N4/ZnV2O6 (1:1) nanocomposite was 6246.1 μmol/g-cat; 1.34 and 1.51 folds higher than g-C3N4/ZnV2O6 (1:1) and ZnV2O6 photocatalysts, respectively. Significant enhancement in quantum efficiency of an externally reflected photoreactor over 4 % rGO-bridged g-C3N4/ZnV2O6 (1:1) nanocomposite was observed compared to the slurry photoreactor. This is obviously because of the greater mobility of charges with hindered recombination rate and higher photonic efficiency. The stability of 4 % rGO-bridged g-C3N4/ZnV2O6 (1:1) nanocomposite was partially reduced after several cyclic runs. It is believed that the photocatalyst consisting of three components has demonstrated improved photocatalytic activity through a S-scheme mechanism, utilizing rGO as an electron mediator to enhance the overall performance of the S-scheme heterojunction.